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29517

Sigma-Aldrich

(S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-dimethylphenyl)phosphine]

≥97%, optical purity ee: ≥99%

Synonym(s):

(S)-2,2′-Bis[bis(3,5-dimethyl)phosphino]-6,6′-dimethoxy-1,1′-biphenyl, (S)-3,5-Xyl-MeOBIPHEP, SL-A120-2

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About This Item

Empirical Formula (Hill Notation):
C46H48O2P2
CAS Number:
362634-22-8
Molecular Weight:
694.82
MDL number:
MFCD09753009
UNSPSC Code:
12352112
PubChem Substance ID:
329753365
NACRES:
NA.22

Quality Level

100

Assay

≥97%

optical purity

ee: ≥99%

functional group

phosphine

SMILES string

COc1cccc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c1-c4c(OC)cccc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6

InChI

1S/C46H48O2P2/c1-29-17-30(2)22-37(21-29)49(38-23-31(3)18-32(4)24-38)43-15-11-13-41(47-9)45(43)46-42(48-10)14-12-16-44(46)50(39-25-33(5)19-34(6)26-39)40-27-35(7)20-36(8)28-40/h11-28H,1-10H3

InChI key

IMUHNRWTDUVXOU-UHFFFAOYSA-N

Related Categories

General description

sold in collaboration with Solvias AG

Application

Atropisomeric MeOBIPHEP ligands

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

29517-VAR:
29517-500MG:
29517-BULK:
29517-5G:
29517-1G:
29517-100MG:

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Certificates of Analysis (COA)

Lot/Batch Number
BCBM6961V
BCCG8734
BCCB8701
BCCB1758
BCBT2489

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Articles

Solvias® Ligand Portfolio for Enantioselective Hydrogenation

Solvias® Ligand Portfolio for Enantioselective Hydrogenation

MeOBIPHEP

Solvias MeOBIPHEP Ligands: State-of-the-art atropisomeric MeOBIPHEP ligands, also referred to as MeO-BIPHEP, originally developed by Roche, have an extraordinarily broad performance profile for many synthetic applications due to their modular ligand design.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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