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Safety Information

281689

Sigma-Aldrich

1,1-Diphenyl-2-picrylhydrazine

97%

Synonym(s):

α,α-Diphenyl-β-picrylhydrazine, 1,1-Diphenyl-2-(2,4,6-trinitrophenyl)hydrazine, 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazine, 2,2-Diphenyl-1-picrylhydrazine, Diphenylpicrylhydrazine

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About This Item

Linear Formula:
2,4,6-(O2N)3C6H2NHN(C6H5)2
CAS Number:
1707-75-1
Molecular Weight:
395.33
Beilstein:
770319
EC Number:
216-953-2
MDL number:
MFCD00007229
UNSPSC Code:
12352100
PubChem Substance ID:
24856989
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

~174 °C (dec.) (lit.)

SMILES string

[O-][N+](=O)c1cc(c(NN(c2ccccc2)c3ccccc3)c(c1)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C18H13N5O6/c24-21(25)15-11-16(22(26)27)18(17(12-15)23(28)29)19-20(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-12,19H

InChI key

WCBPJVKVIMMEQC-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 5: Self-reactive substances
Materials containing Hydrazine derivatives
Hazardous rank I
1st self-reactive materials

JAN Code

281689-5G:
281689-250MG:
281689-BULK:
281689-VAR:
281689-50G:
281689-1G:
281689-1KG:

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ2568
S27679V
05417JE
08810EE
13908LD

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P Smith et al.
Journal of inorganic biochemistry, 31(4), 247-253 (1987-12-01)
In an effort to elucidate the mechanism of the initiation reaction of the denaturation of oxyhemoglobin, I, to methemoglobin, II, by hydrazines, we have investigated by electron paramagnetic resonance, EPR, and visible spectrophotometry at 22 degrees C, pH 7.4, the
The surface reaction between manganese dioxide and 1, 1-diphenyl-2-picrylhydrazine. Two type EPR methods for the estimation of active surface areas of oxides.
Oei ATTT and Garnett JL.
J. Catal., 19(2), 176-194 (1970)
Ji-Yeon Yang et al.
Scientific reports, 7, 45746-45746 (2017-04-01)
Inhibition of α-amylase and α-glucosidase, advanced glycation end products (AGEs) formation, and oxidative stress by isolated active constituents of Osmanthus fragrans flowers (9,12-octadecadienoic acid and 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-buten-2-one) and their structural analogues were evaluated. 9,12-Octadecadienoic acid was 10.02 and 22.21 times more
Na Ji et al.
Food chemistry, 161, 148-154 (2014-05-20)
Peanut protein isolate (PPI) was hydrolysed with alcalase to obtain antioxidant peptides. To purify these peptides, the peanut protein isolate hydrolysates (PPIH) were separated by ultrafiltration (MWCO=3kDa) and the obtained PPIH-II (Mw<3kDa) with higher antioxidant activity was further separated by
Kai Wang et al.
Journal of ethnopharmacology, 155(1), 300-311 (2014-06-03)
Propolis is used widely in a number of cultures as a folk medicine and is gaining wider recognition for its potential therapeutic use, due to its wide range of biological properties and pharmacological activities, especially its anti-inflammatory effects. Despite an
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