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279811

Sigma-Aldrich

Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate

98%

Synonym(s):

Cobaltocenium hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C10H10CoF6P
CAS Number:
12427-42-8
Molecular Weight:
334.08
EC Number:
235-655-3
MDL number:
MFCD00011874
UNSPSC Code:
12161600
PubChem Substance ID:
24856910
NACRES:
NA.22

Quality Level

100

Assay

98%

reaction suitability

core: cobalt
reagent type: catalyst

SMILES string

[Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1

InChI key

IASMSXQWVNBFOM-UHFFFAOYSA-N

Application

Uses:
  • Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
  • Reactant for modification of organometallic electrodes surfaces through cathodic reduction
  • Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

279811-1G:4548173961002
279811-BULK:
279811-VAR:
279811-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM4992
MKCK0176
MKCG1141
MKBX2487V
MKBV5934V

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