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Safety Information

238260

Sigma-Aldrich

1-Iodododecane

98%

Synonym(s):

Dodecyl iodide

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About This Item

Linear Formula:
CH3(CH2)11I
CAS Number:
4292-19-7
Molecular Weight:
296.23
Beilstein:
1738943
EC Number:
224-293-1
MDL number:
MFCD00001088
UNSPSC Code:
12352100
PubChem Substance ID:
24854151
NACRES:
NA.22

Quality Level

100

Assay

98%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.484 (lit.)

bp

159-160 °C/15 mmHg (lit.)

mp

−3 °C (lit.)

density

1.201 g/mL at 25 °C (lit.)

functional group

alkyl halide
iodo

SMILES string

CCCCCCCCCCCCI

InChI

1S/C12H25I/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3

InChI key

GCDPERPXPREHJF-UHFFFAOYSA-N

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General description

SmI2-mediated coupling of 1-iodododecane and 2-octanone in the presence of LiBr, LiCl and hexamethylphosphoramide (HMPA) has been studied.

Application

1-Iodododecane has been used in the preparation of:
  • dodecylated graphite
  • alkyl functionalized single walled carbon nanotubes (SWNTs)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

238260-100G:4548173987033
238260-25G:4548173987040
238260-BULK:
238260-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
STBK0737
STBJ3438
STBJ0554
STBH8900
STBH0104

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Reactions of SmI2 with alkyl halides and ketones: Inner-sphere vs outer-sphere electron transfer in reactions of Sm (II) reductants.
Miller RS, et al.
Journal of the American Chemical Society, 122(32), 7718-7722 (2000)
Robin E Anderson et al.
Journal of nanoscience and nanotechnology, 7(10), 3436-3440 (2008-03-12)
Single walled carbon nanotubes (SWNTs) may be made soluble in a range of organic solvents without sidewall functionalization via their reduction by Na/Hg amalgam in the presence of dibenzo-18-crown-6. The [Na(dibenzo-18-crown-6)]n[SWNT] complex has been characterized by UV-Visible, Raman, and AFM
Functionalization of potassium graphite.
Soma Chakraborty et al.
Angewandte Chemie (International ed. in English), 46(24), 4486-4488 (2007-05-05)
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
Taipeng Shen et al.
Regenerative biomaterials, 5(3), 141-149 (2018-06-27)
Dendritic cell (DC)-based vaccines have shown promising therapeutic results in cancer and some immune disorders. It is critical to track in vivo migration behaviours of DCs and monitor the whole process dynamically and non-invasively. Superparamagnetic iron oxide (SPIO) nanoparticles are
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