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234761

Sigma-Aldrich

Molybdenum(IV) oxide

99%

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About This Item

Linear Formula:
MoO2
CAS Number:
18868-43-4
Molecular Weight:
127.94
EC Number:
242-637-9
MDL number:
MFCD00014223
UNSPSC Code:
12352303
PubChem Substance ID:
24854055
NACRES:
NA.23

Quality Level

100

Assay

99%

form

powder

density

6.47 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

O=[Mo]=O

InChI

1S/Mo.2O

InChI key

QXYJCZRRLLQGCR-UHFFFAOYSA-N

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General description

Molybdenum(IV) oxide (MoO2) is a transition metal oxide with good electrical conductivity due to the presence of delocalized electrons in its valence band. It is traditionally prepared by reducing MoO3 in dry hydrogen in the temperature range of 450-550°C.

Application

MoO2 can be used in a variety of energy based applications such as an anode material in rechargeable lithium batteries and fuel flexible solid oxide fuel cells. It can also be used as a catalyst in hydrogen reforming processes.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

234761-VAR:
234761-50G:4548173932545
234761-10G:4548173932538
234761-25G:
234761-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
STBK2844
STBJ3677
STBH3472
STBG3381V
STBF7334V

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Ordered mesoporous metallic MoO2 materials with highly reversible lithium storage capacity
Shi Y, et al.
Nano Letters, 9(12), 4215-4220 (2009)
Synthesis and applications of molybdenum (IV) oxide
Ellefson CA, et al.
Journal of materials science & technology, 47(5), 2057-2071 (2012)
Sulfur poisoning of molybdenum dioxide during the partial oxidation of a Jet-A fuel surrogate
Marin-Flores O, et al.
Applied Catalysis. B, Environmental, 105(1-2), 61-68 (2011)
Ding Zhou et al.
Nature communications, 5, 4716-4716 (2014-09-03)
Porous graphene, which features nano-scaled pores on the sheets, is mostly investigated by computational studies. The pores on the graphene sheets may contribute to the improved mass transfer and may show potential applications in many fields. To date, the preparation

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