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229601

Sigma-Aldrich

Copper(II) acetate monohydrate

greener alternative

99.99% trace metals basis

Synonym(s):

Cupric acetate monohydrate

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About This Item

Linear Formula:
Cu(CO2CH3)2 · H2O
CAS Number:
6046-93-1
Molecular Weight:
199.65
Beilstein:
3730548
EC Number:
205-553-3
MDL number:
MFCD00149570
UNSPSC Code:
12352103
PubChem Substance ID:
24853290
NACRES:
NA.23

vapor density

6.8 (vs air)

Assay

99.99% trace metals basis

form

powder or crystals

reaction suitability

core: copper

greener alternative product characteristics

Catalysis
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Aligned

SMILES string

O.CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2

InChI key

NWFNSTOSIVLCJA-UHFFFAOYSA-L

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General description

Copper (II) acetate monohydrate is soluble in water and slightly soluble in methanol, diethylether and acetone. It can be synthesized by reacting acetic acid with copper (II) carbonate or copper(II) hydroxide or copper (II) oxide. Large scale commercial production is undertaken by placing copper metal in the presence of air and refluxing acetic acid. As a transition metal acetate, it can be used to form oxide nanoparticles by sonochemical methods.
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Application

Used in the synthesis of copper oxide nanoparticles, Cu2ZnSnS4 films, which find applications in solar cells. It may be used in Zinc Oxide varistors, as a catalyst in the polymerization of organic materials and as a mordant in the dying of textiles. Industrially, it may be used as a ceramic pigment and as a fungicide.

Signal Word

Danger

Hazard Statements

H302,H314,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

does not flash

Flash Point(C)

does not flash

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

229601-BULK:
229601-50G:4548173120416
229601-10G:4548173120409
229601-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Cu2ZnSnS4 films deposited by a soft-chemistry method.
Todorov T, et al.
Thin Solid Films, 517(7), 2541-2544 (2009)
Sonochemical synthesis and characterization of nanometer-size transition metal oxides from metal acetates.
Kumar RV, et al.
Chemistry of Materials, 12(8), 2301-2305 (2000)
Alexander Navarrete et al.
Faraday discussions, 183, 249-259 (2015-09-24)
A novel plasmonic reactor concept is proposed and tested to work as a visible energy harvesting device while allowing reactions to transform CO2 to be carried out. Particularly the reverse water gas shift (RWGS) reaction has been tested as a
Monica L Ohnsorg et al.
Langmuir : the ACS journal of surfaces and colloids, 31(22), 6114-6121 (2015-05-29)
Thin films can integrate the versatility and great potential found in the emerging field of metal-organic frameworks directly into device architectures. For fabrication of smart interfaces containing surface-anchored metal-organic frameworks, it is important to understand how the foundational layers form
Łukasz Orzeł et al.
Dalton transactions (Cambridge, England : 2003), 44(13), 6012-6022 (2015-02-28)
The nature of chlorophyll interactions with copper(II) ions varies considerably in organic solvents, depending on the dominant coordinative form. Besides formation of the metallo tetrapyrrolic complex, Cu(II) ions can cause oxidation of the pigment, reversible or irreversible, which can lead
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