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Safety Information

227307

Sigma-Aldrich

Sodium triethylborohydride solution

1.0 M in toluene

Synonym(s):

Sodium triethylborate, Sodium triethylhydridoborate, Sodium triethylhydroborate

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About This Item

Linear Formula:
(C2H5)3NaBH
CAS Number:
Molecular Weight:
121.99
Beilstein:
4151241
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

1.0 M in toluene

density

0.866 g/mL at 25 °C

SMILES string

[Na+].[H][B-](CC)(CC)CC

InChI

1S/C6H16B.Na/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1

InChI key

YDTZLEUIYNMRLQ-UHFFFAOYSA-N

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Application

Reactant for:
  • Preparation of alcohols by hydrogenation of ketones catalyzed by an iron pincer complex
  • Preparation of alkali metal boron monohydride complexes
  • Coordinative substitution reactions
  • Ligand exchange reactions

  • Hydridic reagent

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

44.6 °F - closed cup

Flash Point(C)

7 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Metal hydrides
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

227307-VAR:
227307-BULK:
227307-800ML:4548173119878
227307-100ML:4548173119861


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