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Safety Information

223301

Sigma-Aldrich

Trioctylphosphine oxide

ReagentPlus®, 99%

Synonym(s):

(Oct)3PO, TOPO®

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About This Item

Linear Formula:
[CH3(CH2)7]3PO
CAS Number:
78-50-2
Molecular Weight:
386.63
Beilstein:
1796648
EC Number:
201-121-3
MDL number:
MFCD00002083
UNSPSC Code:
12352119
PubChem Substance ID:
57647983
NACRES:
NA.22

product line

ReagentPlus®

Assay

99%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.)

functional group

phosphine

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

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Application

Used to extract metals and hydrogen bonding organic compounds. For a review of industrial applications.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
TOPO is a registered trademark of Life Technologies

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H315,H318,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

446.0 °F - closed cup

Flash Point(C)

230 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

223301-BULK:
223301-VAR:
223301-100G:
223301-5G:
223301-25G:
223301-5KG:
223301-1KG:
223301-500G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM7084
MKCJ6344
MKCF0650
MKCC1802
MKBZ0887V

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Solvent Extr. Ion Exch., 10, 879-879 (1992)
Andreas Spinnrock et al.
Nanomaterials (Basel, Switzerland), 9(7) (2019-07-22)
Nanoparticle gradient materials combine a concentration gradient of nanoparticles with a macroscopic matrix. This way, specific properties of nanoscale matter can be transferred to bulk materials. These materials have great potential for applications in optics, electronics, and sensors. However, it
Alasdair A M Brown et al.
Nanoscale, 11(25), 12370-12380 (2019-06-20)
We report the self-assembly of an extensive inter-ligand hydrogen-bonding network of octylphosphonates on the surface of cesium lead bromide nanocrystals (CsPbBr3 NCs). The post-synthetic addition of octylphosphonic acid to oleic acid/oleylamine-capped CsPbBr3 NCs promoted the attachment of octylphosphonate to the
Alex Khammang et al.
Nature communications, 12(1), 438-438 (2021-01-21)
In terms of producing new advances in sustainable nanomaterials, cation exchange (CE) of post-processed colloidal nanocrystals (NCs) has opened new avenues towards producing non-toxic energy materials via simple chemical techniques. The main processes governing CE can be explained by considering
Shuang-Yuan Zhang et al.
Advanced materials (Deerfield Beach, Fla.), 24(32), 4369-4375 (2012-07-19)
The preparation of vertically or horizontally aligned self-assemblies of CoP nanowires is demonstrated for the first time by aging them in the reaction solution for a sufficient time at 20 or 0 °C. This strategy opens up a way for
View All Related Papers

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