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220558

Sigma-Aldrich

Ethyl 2-aminothiazole-4-acetate

99%

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About This Item

Empirical Formula (Hill Notation):
C7H10N2O2S
CAS Number:
53266-94-7
Molecular Weight:
186.23
Beilstein:
139617
EC Number:
258-452-1
MDL number:
MFCD00005330
UNSPSC Code:
12352100
PubChem Substance ID:
24853177
NACRES:
NA.22
Assay:
99%

Quality Level

200

Assay

99%

mp

92-94 °C (lit.)

functional group

ester

SMILES string

CCOC(=O)Cc1csc(N)n1

InChI

1S/C7H10N2O2S/c1-2-11-6(10)3-5-4-12-7(8)9-5/h4H,2-3H2,1H3,(H2,8,9)

InChI key

SHQNGLYXRFCPGZ-UHFFFAOYSA-N

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General description

Ethyl 2-aminothiazole-4-acetate is an organic ligand and possess strong coordination ability and display diverse coordination modes due to the presence of N, O coordination atoms.

Application

Ethyl 2-aminothiazole-4-acetate was used in the synthesis of:
  • bis (2-aminothiazole-4-acetato)aquazinc(II)
  • dichloridobis[ethyl 2-(2-amino-1, 3-thiazol-4-yl) acetate-κ2O,N3]cadmium
  • novel heteroaryl-containing benzamide derivatives

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

365.0 °F - closed cup

Flash Point(C)

185 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

220558-VAR:
220558-250G:
220558-BULK:
220558-50G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCBJ8096V
1383369V
00909DJ
1383369
452811/1

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Lai-Jun Zhang et al.
Acta crystallographica. Section E, Structure reports online, 65(Pt 12), m1517-m1517 (2009-01-01)
In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn-N = 2.047 (3) Å, Zn-O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a
Lai-Jun Zhang et al.
Acta crystallographica. Section E, Structure reports online, 68(Pt 6), m788-m789 (2012-06-22)
The asymmetric unit of the title compound, [CdCl(2)(C(7)H(10)N(2)O(2)S)(2)], contains two complex molecules with similar configurations. The Cd(II) atoms are each six-coordinated by two thiazole N and two carbonyl O atoms from the 2-(2-amino-1,3-thiazol-4-yl)acetate ligand, and by two Cl(-) anions in
Kaapjoo Park et al.
Bioorganic & medicinal chemistry, 22(7), 2280-2293 (2014-03-05)
Novel heteroaryl-containing benzamide derivatives were synthesized and screened using an in vitro assay measuring increases in glucose uptake and glucokinase activity stimulated by 10mM glucose in rat hepatocytes. From a library of synthesized compounds, 3-(4-methanesulfonylphenoxy)-N-[1-(2-methoxy-ethoxymethyl)-1H-pyrazol-3-yl]-5-(3-methyl pyridin-2-yl)-benzamide (19e) was identified as

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