Skip to Content
Merck
All Photos(1)

Key Documents

Safety Information

209864

Sigma-Aldrich

4-tert-Butylaniline

99%

Synonym(s):

4-(1,1-Dimethylethyl)aniline, 4-(1,1-Dimethylethyl)benzenamine, 4-Amino-tert-butylbenzene, 4-t-Butylphenylamine, 4-tert-Butylbenzenamine, 4-tert-Butylphenylamine, p-(tert-Butyl)phenylamine, p-tert-Butylaniline

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3CC6H4NH2
CAS Number:
Molecular Weight:
149.23
Beilstein:
2205786
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

liquid

refractive index

n20/D 1.538 (lit.)

bp

90-93 °C/3 mmHg (lit.)

mp

15-16 °C (lit.)

density

0.937 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)c1ccc(N)cc1

InChI

1S/C10H15N/c1-10(2,3)8-4-6-9(11)7-5-8/h4-7H,11H2,1-3H3

InChI key

WRDWWAVNELMWAM-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Schiff base formation reaction between 4-tert-butylaniline and 4-tert-butylbenzaldehyde in ethanol has been carried out using the matrix-assisted laser desorption ionization-chip system.

Application

4-tert-Butylaniline was used in the synthesis of:
  • 4-tert-Butyl-4′,4″-dinitrotriphenylamine, new triphenylamine-containing diamine monomer
  • 2-oxopyrimido[4,5-d]pyrimidin-5(6H)-one

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

215.6 °F - closed cup

Flash Point(C)

102 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

209864-5G:
209864-BULK:
209864-VAR:
209864-25G:


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Self-complementary hydrogen bonding heterocycles designed for the enforced self-assembly into supramolecular macrocycles.
Marsh A, et al.
Chemical Communications (Cambridge, England), 13, 1527-1528 (1996)
Christopher G Thomson et al.
Bioorganic & medicinal chemistry letters, 21(14), 4281-4283 (2011-06-15)
A novel and robust synthesis of the fragment, 2-amino-5-tert-butylpyridine, has been described, which has been shown to have improved physicochemical properties over 4-tert-butylaniline, when considering drug-like properties. The synthesis also yields fragments containing more highly oxidised precursors to the tert-butyl
Novel aromatic polyamides and polyimides functionalized with 4-tert-butyltriphenylamine groups.
Hsiao S-H, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(15), 4579-4592 (2006)
Monica Brivio et al.
Lab on a chip, 5(4), 378-381 (2005-03-26)
The integration of a monitoring port along the microfluidic path of a MALDI-chip integrated device is described. Optimization of the microreactor design allows longer reaction and measuring times. The Schiff base reaction between 4-tert-butylaniline (1) and 4-tert-butylbenzaldehyde (2) in ethanol
Ji Han Kim et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(38), 9060-9070 (2019-04-16)
Organic light-emitting diodes are currently under research to achieve high efficiency and long life by using thermally activated delayed fluorescence (TADF) materials. In particular, many studies have focused on ensuring high efficiency in fluorescent devices by introducing TADF materials. Herein

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service