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Safety Information

206113

Sigma-Aldrich

Platinum(IV) chloride

96%

Synonym(s):

Platinum tetrachloride

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About This Item

Linear Formula:
PtCl4
CAS Number:
Molecular Weight:
336.89
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38191307
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

96%

form

powder and chunks

reaction suitability

reagent type: catalyst
core: platinum

mp

370 °C (dec.) (lit.)

density

4.303 g/mL at 25 °C (lit.)

SMILES string

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

InChI key

FBEIPJNQGITEBL-UHFFFAOYSA-J

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Application

Platinum(IV) chloride can be used as a precursor to synthesize Pt-based nanocatalysts for various organic transformations. For example, Carbon-supported Pt-Ru nanoparticles can be used as an efficient catalyst for methanol and ethanol oxidation.

Due to its high affinity to the glycosyl acceptor hydroxy groups and bidentate ligation capacity, it can be used as a dual catalyst for regio- and stereoselective glycosidation reactions.

It can also be used for the photosensitization and surface modification of TiO2 for the photodegradation of 4-chlorophenol.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

206113-BULK:
206113-1G:4548173981550
206113-VAR:
206113-250MG:4548173981567
206113-5G:4548173981574


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N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
Eric Ennifar et al.
Nucleic acids research, 31(10), 2671-2682 (2003-05-09)
Metal ions, and magnesium in particular, are known to be involved in RNA folding by stabilizing secondary and tertiary structures, and, as cofactors, in RNA enzymatic activity. We have conducted a systematic crystallographic analysis of cation binding to the duplex
B A Teicher et al.
Anticancer research, 13(5A), 1549-1556 (1993-09-01)
Since several anticancer drugs are known to become more cytotoxic to cells in an acidic milieu, we have attempted to utilize the carbonic anhydrase inhibitor, Acetazolamide, to acidify the blood and tumor of C3H mice bearing the FSaIIC fibrosarcoma in
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect

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