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201049

Sigma-Aldrich

Lithium hydride

greener alternative

powder, −30 mesh, ≥95%

Synonym(s):

LiH

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About This Item

Linear Formula:
LiH
CAS Number:
Molecular Weight:
7.95
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥95%

form

powder

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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particle size

−30 mesh

mp

680 °C (lit.)

density

0.82 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li]

InChI

1S/Li.H

InChI key

SIAPCJWMELPYOE-UHFFFAOYSA-N

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General description

Lithium hydride is a simple neutral heteropolar diatomic molecule. It liberates hydrogen upon heating it to temperatures above 500oC. Lithium hydride, like lithium aluminum hydride, exhibits a high gravimetric hydrogen storage capacity. LiH is known to have large specific heat and latent heat of fusion.5
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Application

Lithium hydride may be used as an effective neutron shield for mobile nuclear reactors. LiH may also be used as a rocket fuel, energy storage system, and heat shield.5

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B - Water-react 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Metal hydrides
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

201049-VAR:
201049-10G:4548173921839
201049-BULK:
201049-500G:4548173930008
201049-100G:4548173929996
201049-5G:4548173930015
201049-10KG:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Lithium hydride: A space age shielding material
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Spectroscopy and structure of the lithium hydride diatomic molecules and ions.
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The Journal of Physical Chemistry, 22(1), 87-112 (1993)
Thermophysical Properties of Chemicals and Hydrocarbons null
Volodymyr Gvozdetskyi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(16), 4123-4135 (2019-01-17)
Ternary lithium nickel borides LiNi3 B1.8 and Li2.8 Ni16 B8 have been synthesized by using reactive LiH as a precursor. This synthetic route allows better mixing of the precursor powders, thus facilitating rapid preparation of the alkali-metal-containing ternary borides. This
Nikola Biliškov et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(64), 16274-16282 (2017-09-14)
For the first time, in situ monitoring of uninterrupted mechanochemical synthesis of two bimetallic amidoboranes, M

Articles

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Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids

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