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Safety Information

188360

Sigma-Aldrich

(1R)-(−)-10-Camphorsulfonic acid ammonium salt

98%

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About This Item

Empirical Formula (Hill Notation):
C10H19NO4S
CAS Number:
Molecular Weight:
249.33
EC Number:
MDL number:
UNSPSC Code:
12352115
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

solid

optical activity

[α]22/D −18.4°, c = 5.3 in H2O

mp

250 °C (dec.) (lit.)

functional group

ketone
sulfonic acid

SMILES string

N.CC1(C)[C@H]2CC[C@]1(CS(O)(=O)=O)C(=O)C2

InChI

1S/C10H16O4S.H3N/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14;/h7H,3-6H2,1-2H3,(H,12,13,14);1H3/t7-,10-;/m0./s1

InChI key

JTMZBRWRXFAITF-YUWZRIFDSA-N

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General description

(1R)-(-)-10-Camphorsulfonic acid ammonium salt may be used as an ion-pair reagent to enhance the ability of supercritical carbon dioxide to extract polar compounds in supercritical fluid extraction (SFE) process. It can also be used in the synthesis of (-)-quadrone.

Application

Reactant involved in the synthesis of chiral anionic liquids for use as solvents and chiral shift reagents

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

188360-50G:
188360-BULK:
188360-VAR:


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Ion-pair-supercritical fluid extraction of clenbuterol from food samples.
Jimenez-Carmona MM, et al.
Journal of Chromatography A, 711(2), 269-276 (1995)
Sub-and supercritical fluid extraction of trichloropyridinol from soil prior to immunoassay.
Jimenez-Carmona MM, et al.
Journal of Chromatography A, 785(1-2), 329-336 (1997)
Total synthesis of natural quadrone.
Liu HJ and Llinas-Brunet M.
Canadian Journal of Chemistry, 66(3), 528-530 (1988)

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