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163694

Sigma-Aldrich

2,4,6-Tribromoaniline

98%

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About This Item

Linear Formula:
Br3C6H2NH2
CAS Number:
147-82-0
Molecular Weight:
329.81
Beilstein:
2209258
EC Number:
205-700-1
MDL number:
MFCD00007634
UNSPSC Code:
12352100
PubChem Substance ID:
24850033
NACRES:
NA.22

Assay

98%

form

powder

bp

300 °C (lit.)

mp

120-122 °C (lit.)

solubility

alcohol: soluble (cold)(lit.)
alcohol: soluble (hot)(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)

functional group

bromo

SMILES string

Nc1c(Br)cc(Br)cc1Br

InChI

1S/C6H4Br3N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2

InChI key

GVPODVKBTHCGFU-UHFFFAOYSA-N

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General description

Electrochemical oxidation of 2,4,6-tribromoaniline in aqueous sulphuric acid solutions at platinum electrode has been studied by rotating disc electrode and cyclic voltammetry. 2,4,6-Tribromoaniline on closed-tube pyrolysis yields polybromophenazines. It is an intermediate in the formulation of flame retardants incorporated to plastic materials.

Application

2,4,6-Tribromoaniline was used in simultaneous determination of phenolic brominated flame retardants and their by-products in water.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H317,H319,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

163694-500G:
163694-BULK:
163694-VAR:
163694-100G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB2072
BCBX0764
BCBV2863
BCBQ6200V
BCBK9365V

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Formation of bromodioxin analogs from closed tube pyrolysis of 2, 4, 6-tribromoaniline (I).
Alsabbagh AM, et al.
Chemosphere, 17(12), 2391-2396 (1988)
Voltammetric study of the oxidation kinetics of 2, 4, 6,-tribromoaniline in acid medium.
Brillas E, et al.
J. Electroanal. Chem. Interfac. Electrochem., 160(1), 185-198 (1984)
P López et al.
Journal of chromatography. A, 1216(3), 334-345 (2008-09-03)
Brominated flame retardants (BFRs) are the chemicals of high importance within the REAch framework. In addition to polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA), other BFRs such as bromophenols, intermediates in FR formulation like bromoanilines, and their

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