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Safety Information

148113

Sigma-Aldrich

2,6-Diaminotoluene

97%

Synonym(s):

2,6-Toluenediamine, 2,6-Tolylenediamine, 2-Methyl-m-phenylenediamine

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About This Item

Linear Formula:
CH3C6H3(NH2)2
CAS Number:
823-40-5
Molecular Weight:
122.17
Beilstein:
2079476
EC Number:
212-513-9
MDL number:
MFCD00007800
UNSPSC Code:
12162002
PubChem Substance ID:
24848882
NACRES:
NA.23

Quality Level

100

Assay

97%

form

solid

mp

104-106 °C (lit.)

SMILES string

Cc1c(N)cccc1N

InChI

1S/C7H10N2/c1-5-6(8)3-2-4-7(5)9/h2-4H,8-9H2,1H3

InChI key

RLYCRLGLCUXUPO-UHFFFAOYSA-N

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Muta. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class II Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

148113-5G:4548173105895
148113-VAR:
148113-5KG:
148113-BULK:
148113-500G:
148113-25G:4548173105888
Q148113-BULK:
Q148113-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
STBK8598
STBK4621
STBG9075
STBG4660V
S29601V

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H Tinnerberg et al.
American Industrial Hygiene Association journal, 58(3), 229-235 (1997-03-01)
Comparative air measurements of toluene diisocyanate (TDI) were performed in a 5.6 m3 standard atmosphere and at a TDI flexible foam plant. Air samples were collected in midget impinger flasks containing 9-(N-methyl-amino-methyl)-anthracene (MAMA) in toluene and on 13-mm glass-fiber filters
Hironao Takasawa et al.
Mutation research, 751(1), 12-18 (2012-11-06)
Detecting genotoxicity in the liver is considered an effective approach for predicting hepatocarcinogenicity, as many genotoxic chemicals in vivo may act as hepatocarcinogens in rodents. Here, a genotoxic rodent hepatocarcinogen, 1,2-dimethylhydrazine dihydrochloride (1,2-DMH), and a genotoxic (Ames positive) noncarcinogen, 2,6-diaminotolunene
P M Wilson et al.
Archives of toxicology, 70(10), 591-598 (1996-01-01)
Using gas chromatography/mass spectrometry for detection of hemoglobin adducts, and 32P-postlabelling for DNA adducts, we examined macromolecular binding in Fischer-344 rats administered 2,4-or 2,6-toluene diamine (TDA). The dose-response and correlative relationship between the two macromolecules were investigated over a range
O Sepai et al.
Toxicology letters, 77(1-3), 371-378 (1995-05-01)
Toluenediamines (TDA) were monitored in blood, urine and redon drainage following implantation of polyurethane (PU)-covered breast prostheses. In the redon drainage TDAs showed an initial steep drop. The levels did not fall below detection limits but formed a plateau, which
B M Miller et al.
Environmental and molecular mutagenesis, 26(3), 240-247 (1995-01-01)
A rapid and simple procedure for the micronucleus test (MNT) in vitro using Chinese hamster ovary (CHO) cells was established in our laboratory. The assay is intended to quickly screen chromosomal aberrations in vitro within the framework of industrial genotoxicity
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