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Safety Information

130915

Sigma-Aldrich

2-Bromophenol

98%

Synonym(s):

o-Bromophenol

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About This Item

Linear Formula:
BrC6H4OH
CAS Number:
95-56-7
Molecular Weight:
173.01
Beilstein:
1905115
EC Number:
202-432-7
MDL number:
MFCD00002146
UNSPSC Code:
12352100
PubChem Substance ID:
24847983
NACRES:
NA.22

Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.589 (lit.)

bp

195 °C (lit.)

mp

3-7 °C (lit.)

density

1.492 g/mL at 25 °C (lit.)
1.6235 g/mL at 25 °C

SMILES string

Oc1ccccc1Br

InChI

1S/C6H5BrO/c7-5-3-1-2-4-6(5)8/h1-4,8H

InChI key

VADKRMSMGWJZCF-UHFFFAOYSA-N

Gene Information

human ... ALOX12(239) , ALOX15(246)

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Application

2-Bromophenol was used in the preparation of anti-benzofurobenzofuran diimides. It was also used to study the photodegradation of 2-bromophenol using UV-Vis spectroscopy and HPLC.

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

107.6 °F - closed cup

Flash Point(C)

42 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

130915-10G:
130915-BULK:
130915-50G:
130915-1G:
130915-500G:
130915-VAR:
130915-1KG:

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Certificates of Analysis (COA)

Lot/Batch Number
STBK6329
STBK1064
STBJ9790
STBJ7657
STBH8232

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Sabin-Lucian Suraru et al.
The Journal of organic chemistry, 79(1), 128-139 (2013-11-28)
Here we report a selective method for the core-extension of naphthalene diimide (NDI) with two annulated indole rings leading to carbazolo[2,3-b]carbazole diimides (CbDIs) with exclusive syn-connectivity based on a regioselective nucleophilic substitution reaction of Br4-NDI with arylamines, followed by palladium-catalyzed
Catherine S Evans et al.
Environmental science & technology, 39(7), 2128-2134 (2005-05-06)
The homogeneous, gas-phase oxidative thermal degradation of 2-bromophenol was studied in a 1 cm i.d., fused silica flow reactor at a concentration of 88 ppm, reaction time of 2.0 s, over a temperature range from 300 to 1000 degrees C.
Christian Eidamshaus et al.
Organic letters, 10(19), 4211-4214 (2008-08-30)
A one-pot synthesis of benzofurans which utilizes a palladium-catalyzed enolate arylation is described. The process demonstrates broad substrate scope and provides differentially substituted benzofurans in moderate to excellent yields. The utility of the method is further demonstrated by the synthesis
Miho Uchida et al.
Journal of hazardous materials, 101(3), 231-238 (2003-08-26)
2-Bromophenol was reacted in aqueous sodium hydroxide at 200-250 degrees C. The decomposition rate was remarkably faster at 250 degrees C than at 225 or 200 degrees C, and the percentage debromination reached almost 100% in 1M NaOH at 250
Catherine S Evans et al.
Environmental science & technology, 40(9), 3036-3042 (2006-05-25)
The homogeneous, gas-phase oxidative thermal degradation of a 50:50 mixture of 2-bromophenol and 2-chlorophenol was studied in a 1 cm i.d., fused silica flow reactor at a concentration of 88 ppm, with a reaction time of 2.0 s, over a
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US EPA Method 8041: GC Analysis of Phenols on Equity®-5

Separation of 2-Chlorophenol; 2,4-Dichlorophenol; 2,4,6-Tribromophenol; 2,4,6-Trichlorophenol; 2,4-Dinitrophenol; Pentafluorophenol; 2-Methylphenol, analytical standard; 2,3,4,6-Tetrachlorophenol; Pentachlorophenol; 4-Nitrophenol; 2-Bromophenol; 2,3,5,6-Tetrachlorophenol; 2,3,5-Trichlorophenol; 4-Chloro-3-methylphenol; 2,4,5-Trichlorophenol; 4-Methylphenol, analytical standard; 2,4-Dimethylphenol; 2-Nitrophenol; 3-Methylphenol, analytical standard; Phenol; 2-Methyl-4,6-dinitrophenol; 2,3,4-Trichlorophenol; 2,6-Dichlorophenol; 2,3,4,5-Tetrachlorophenol

Protocols

GC Analysis of Phenols in Water on a 5% Phenyl Column after SPE using Supelclean™ ENVI-Chrom P

Separation of 2-Nitrophenol; Pentachlorophenol; 2-Bromophenol; Phenol; 4-Nitrophenol; 3-Methylphenol, analytical standard; 4-Chloro-3-methylphenol; 2,4-Dichlorophenol; 2,3,4,6-Tetrachlorophenol; 2-Methylphenol, analytical standard; 2,4,6-Trichlorophenol; 2,4-Dimethylphenol; 2-Chlorophenol

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