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110779

Sigma-Aldrich

Ethylidenecyclohexane

99%

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About This Item

Linear Formula:
C6H10(=CHCH3)
CAS Number:
1003-64-1
Molecular Weight:
110.20
EC Number:
213-711-8
MDL number:
MFCD00001662
UNSPSC Code:
12352100
PubChem Substance ID:
24847003
NACRES:
NA.22

Assay

99%

refractive index

n20/D 1.462 (lit.)

bp

136 °C (lit.)

density

0.822 g/mL at 25 °C (lit.)

SMILES string

C\C=C1\CCCCC1

InChI

1S/C8H14/c1-2-8-6-4-3-5-7-8/h2H,3-7H2,1H3

InChI key

BPBOWYWUOUJKLO-UHFFFAOYSA-N

General description

Ethylidenecyclohexane is oxidized by purified ethylbenzene dehydrogenase.

Application

Ethylidenecyclohexane has been used as a substrate in the Lewis-acid catalyzed reactions of azodicarboxylates with different alkenes.

Pictograms

Flame
GHS02

Signal Word

Warning

Hazard Statements

H226

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

75.2 °F - closed cup

Flash Point(C)

24 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

110779-BULK:
110779-10G:
110779-VAR:
110779-25G:
110779-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN1644
MKCL7085
MKCL5594
MKBH6738V
MKBF6748V

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H A Johnson et al.
Journal of bacteriology, 183(15), 4536-4542 (2001-07-10)
The first step in anaerobic ethylbenzene mineralization in denitrifying Azoarcus sp. strain EB1 is the oxidation of ethylbenzene to (S)-(-)-1-phenylethanol. Ethylbenzene dehydrogenase, which catalyzes this reaction, is a unique enzyme in that it mediates the stereoselective hydroxylation of an aromatic
Pompiliu S Aburel et al.
Organic & biomolecular chemistry, 3(12), 2344-2349 (2005-07-13)
Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichloroethyl)azodicarboxylate as the amination reagent and Cu(OTf)(2) and Yb(OTf)(3) as the catalysts gave the aza-ene

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