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Key Documents

CRM67566

Supelco

Metalaxyl-M

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Sinonimo/i:

N-(2,6-Dimethylphenyl)-N-(methoxyacetyl)-D-alanine methyl ester, Mefenoxam

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About This Item

Formula empirica (notazione di Hill):
C15H21NO4
Numero CAS:
Peso molecolare:
279.33
Numero MDL:
Codice UNSPSC:
41116107
NACRES:
NA.24

Grado

certified reference material
TraceCERT®

Livello qualitativo

Nome Commerciale

TraceCERT®

Durata

limited shelf life, expiry date on the label

Produttore/marchio commerciale

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Stringa SMILE

COCC(=O)N([C@H](C)C(=O)OC)c1c(C)cccc1C

InChI

1S/C15H21NO4/c1-10-7-6-8-11(2)14(10)16(13(17)9-19-4)12(3)15(18)20-5/h6-8,12H,9H2,1-5H3/t12-/m1/s1
ZQEIXNIJLIKNTD-GFCCVEGCSA-N

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Descrizione generale

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Metalaxyl-M is the R-enantiomer of the systemic fungicide metalaxyl. It is a widely used acetylalanine fungicide.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, metalaxyl-M is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2020/617 of 5th May 2020 renewed the approval of use for metalaxyl-M in products of plant origin until 31st May 2035. The Reg. (EU) 2017/1164 sets a maximum residue limit (MRL) of 0.7 mg/kg and 0.01 mg/kg in fresh/frozen fruits and tree nuts respectively for metalaxyl including other mixtures of constituent isomers including metalaxyl-M (sum of isomers).
Metalaxyl-M has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Applicazioni

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The metalaxyl-M CRM may also find following uses:
  • Mixed-mode solid phase extraction (SPE) and liquid chromatographic-mass spectrometric (LC-MS) determination of 9 fungicides in red and white wine samples
  • Analyze the uptake and distribution of two fungicides and two insecticides in greenhouse grown chrysanthemum by QuEChERS-based extraction from the root, stem, leaf, flower, and soil samples, followed by an UPLC-MS/MS determination
  • Simultaneous determination of six fungicides residues in grape, wine, and raisin samples by HPLC-MS/MS
  • Separation of 21 chiral pesticides by supercritical fluid chromatography-mass spectrometry (SFC-ESIMS/MS) from tomato, orange, leek, and cayenne samples
  • Investigation of 109 pesticide residues in gherkin samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Multi-residue analysis of 58 pesticide residues in water samples by extraction using solvent-based de-emulsification dispersive liquid-liquid microextraction (SD-DLLME) and determination by liquid chromatography-tandem mass spectrometry (LC-MS/MS)

Note legali

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

CorrosionExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Eye Dam. 1

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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Víctor Cutillas et al.
Journal of chromatography. A, 1620, 461007-461007 (2020-03-11)
Evaluation of chiral pesticides remains a frequently neglected matter in routine food control laboratories. This fact is due to the existence of many residue definitions but also due to the lack of robust instrumental methods for the evaluation of these
I Carpinteiro et al.
Journal of chromatography. A, 1217(48), 7484-7492 (2010-10-26)
A novel procedure for the determination of nine selected fungicides (metalaxyl-M, azoxystrobin, myclobutanil, flusilazole, penconazole, tebuconazole, propiconazole, diniconazole and difenoconazole) in wine samples is presented. Sample enrichment and purification is simultaneously performed using mixed-mode, anion exchange and reversed-phase, OASIS MAX
Quantification of pesticide residues in gherkins by liquid and gas chromatography coupled to tandem mass spectrometry
Golge O, et al.
Journal of food composition and analysis, 96, 103755-103755 (2021)
Rapid analysis and residue evaluation of six fungicides in grape wine-making and drying
Hou X, et al.
Journal of food composition and analysis, 89, 103465-103465 (2020)

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