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Documenti fondamentali

10464-U

Supelco

Carbopack™ Adsorbent

matrix Carbopack™ Y, 120-400 mesh, bottle of 50 g

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About This Item

Numero CE:
215-609-9
Codice UNSPSC:
23201100
NACRES:
SB.54

Nome Commerciale

Carbopack™

Stato

granular

Confezionamento

bottle of 50 g

tecniche

LPLC: suitable

Area superficiale

~24 m2/g

Matrice

Carbopack™ Y

Gruppo funzionale matrice

carbon

Dimensione particelle

120-400 mesh

Dimensione pori

~0 cm3/g macroporosity
~0 cm3/g mesoporosity
~0 cm3/g microporosity
~0 Å pore diameter

Densità

~0.38 g/mL (free fall density)

Tecnica di separazione

reversed phase

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Descrizione generale

A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
  • Granular
  • Friable
  • Used for molecules with an analyte size relative to C3-C20+ n-alkanes
  • Hydrophobic (can be used in high humidity environments)

Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
  • Particles are 40 mesh and smaller
  • Use 40/60 mesh to prevent channeling (if observed with a 20/40 mesh Carbotrap® adsorbent)
  • Use smaller mesh (60/80, 80/100, etc.) for all other applications
  • Use the smallest particle size available as long as the application can handle the pressure drop

For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
Carbotrap®/Carbopack™ adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly. Carbotrap®/Carbopack™ adsorbent was used to quantitatively determine trace amounts of volatile organic compounds (VOCs) in air. It was also used for designing sampling protocols on the basis of its retention volume of the gaseous organic compounds of interest.

Applicazioni

Carbopack™ Y was used for determination of contamination caused by pesticides like alachlor, atrazine, captan, formothion, lindane and phosalone in atmospheric samples. Carbopack™ Y was modified with mono-molecular layer of heptakis-(2,3,6-tri-O-methyl)-ß-cyclodextrin and was used in gas chromatography to study the effect of size and spatial structure of adsorbate molecules on adsorption of organic vapours.

Note legali

Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

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Certificati d'analisi (COA)

Lot/Batch Number

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Adsorption of organic vapors on the Carbopack Y carbon adsorbent modified with heptakis-(2, 3, 6-tri-O-methyl)-?-cyclodextrin.
Kudryashov SY, et al.
Russian Journal of Physical Chemistry A, 84 (3), 495-502 (2010)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)
Gas phase retention volume behavior of organic compounds on Carbotrap graphitized carbon.
Pankow JF.
Journal of Chromatography A, 547, 488-493 (1991)
Plant Volatile Analysis.
Linskens HF and Jackson JF.
Modern Methods of Plant Analysis, 19, 54-56 (1997)
Li-Ming Yuan et al.
Analytical chemistry, 78(18), 6384-6390 (2006-09-15)
Single-walled carbon nanotubes (SWNTs) have high surface area, high adsorption ability, and nanoscale interactions. In this study, capillary columns including SWNTs, ionic liquid (IL), and IL + SWNTs for GC were prepared. The separation results showed that SWNTs possessed a
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