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Key Documents

89928

Supelco

Azinphos-methyl-(dimethyl-d6)

PESTANAL®, analytical standard

Sinonimo/i:

Azinphos-methyl-d6, Methyltriazotin-d6

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About This Item

Formula empirica (notazione di Hill):
C10D6H6N3O3PS2
Peso molecolare:
323.36
Numero MDL:
Codice UNSPSC:
12352200
ID PubChem:
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

Nome Commerciale

PESTANAL®

Saggio

≥98.0% (HPLC)

Durata

limited shelf life, expiry date on the label

applicazioni

agriculture

Formato

neat

Temperatura di conservazione

2-8°C

Stringa SMILE

O=C1N(CSP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)N=NC2=CC=CC=C21

InChI

1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3/i1D3,2D3
CJJOSEISRRTUQB-WFGJKAKNSA-N

Categorie correlate

Descrizione generale

Azinphos-methyl-(dimethyl-d6) is an isotope-labeled analog of the organophosphorus anticholinesterase insecticide azinphos-methyl, wherein dimethoxy protons are substituted by deuterium.

Applicazioni

Azinphos-methyl-(dimethyl-d6) may be used as a deuterated internal standard to determine the levels of pesticide analytes in foods, fruits and vegetable matrices by gas chromatography (GC) based techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Note legali

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Skull and crossbonesEnvironment

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Codice della classe di stoccaggio

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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Combined use of a modifier gas generator, analyte protectants and multiple internal standards for effective and robust compensation of matrix effects in gas chromatographic analysis of pesticides
Tsuchiyama T, et al.
Journal of Chromatography A, 1589(3), 122-133 (2019)
Effects of carbaryl and azinphos methyl on juvenile rainbow trout (Oncorhynchus mykiss) detoxifying enzymes
Ferrari A, et al.
Pesticide Biochemistry and Physiology, 88(2), 134-142 (2007)
Ali Özcan et al.
Water research, 47(3), 1470-1479 (2013-01-02)
The removal of organophosphorous insecticide azinphos-methyl (AZPM) from water has been investigated by the electro-Fenton method which produces hydroxyl radicals electro-catalytically. The reaction between these radicals and AZPM has led to the oxidation of AZPM up to carbon dioxide and

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