931845

GenOx-PJ

• Sinonimo/i: 3-Oxo-2-tosyl-2,3-dihydro-1H-1λ₃-benzo[d][1,2]iodazol-1-yl acetate
• Formula empirica (notazione di Hill): C₁₆H₁₄INO₅S
• Numero CAS: 2243393-44-2
• Peso molecolare: 459.26
• Codice UNSPSC: 12352200
• NACRES: NA.21

Proprietà

• Forma fisica: powder
• Livello qualitativo: 100
• Punto di fusione: >300 °C
• Gruppo funzionale: iodo
• Temperatura di conservazione: −20°C

Descrizione

Applicazioni

GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.

Altre note

A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon−Oxygen Bond Formation

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable