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759546

Sigma-Aldrich

Lithium iron(II) phosphate

greener alternative

powder, <5 μm particle size (BET), >97% (XRF)

Sinonimo/i:

Ferrous lithium phosphate, Iron lithium phosphate, LFP, Triphylite

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About This Item

Formula condensata:
LiFePO4
Numero CAS:
Peso molecolare:
157.76
Codice UNSPSC:
26111700
NACRES:
NA.23

Grado

battery grade

Livello qualitativo

Saggio

>97% (XRF)

Forma fisica

powder

PM

Mw 157.76 g/mol

Composizione

LiFePO4

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Dimensione particelle

<5 μm (BET)

Punto di fusione

>300 °C (lit.)

Densità

3.6 g/cm3 (lit.)

applicazioni

battery manufacturing

Categoria alternativa più verde

InChI

1S/Fe.Li.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q+2;+1;/p-3
GELKBWJHTRAYNV-UHFFFAOYSA-K

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Descrizione generale

Lithium iron(II) phosphate (LiFePO4), also called LFP, is a crystalline, grey-to-black powder with an olivine crystal structure. This unique structure facilitates efficient diffusion of lithium-ions, thanks to the three-dimensional interconnected iron phosphate tetrahedra that form pathways for lithium ions to diffuse. Additionally, the structure is highly stable, not deforming, even after thousands of cycles of lithium intercalation. Our LiFePO4 powder is manufactured to meet high purity with a tightly controlled particle size of less than 5 μm.
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Applicazioni

LiFePO4 is a widely used cathode for rechargeable Li batteries. It has high energy density, wide operating temperature, thermal stability, long cycle life and application life, environmental friendliness, and safety that make it a promising electrode material for greener and safer lithium-ion batteries.

Caratteristiche e vantaggi

LiFePO4-based batteries can last longer, operate safely and reliably, and power devices in a wide range of temperatures.
✔ Achieves 1000s of cycles
✔ Safer than cobalt or manganese-based cathode materials
✔ Reliable performance

Note legali

Product of Engi-Mat Co.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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P Subramanya Herle et al.
Nature materials, 3(3), 147-152 (2004-03-03)
The provision of efficient electron and ion transport is a critical issue in an exciting new group of materials based on lithium metal phosphates that are important as cathodes for lithium-ion batteries. Much interest centres on olivine-type LiFePO(4), the most
Kim, G. T.; et al.
Journal of Power Sources, 196, 2187-2187 (2011)
Low temperature hydrothermal synthesis of battery grade lithium iron phosphate
Benedek P, et al.
Royal Society of Chemistry Advances, 7(29), 17763-17767 (2017)
Byoungwoo Kang et al.
Nature, 458(7235), 190-193 (2009-03-13)
The storage of electrical energy at high charge and discharge rate is an important technology in today's society, and can enable hybrid and plug-in hybrid electric vehicles and provide back-up for wind and solar energy. It is typically believed that

Articoli

Professor Qiao’s laboratory lays out recent advances in conversion type lithium metal fluoride batteries. This review explores key concepts in developing electrochemically stable microstructures for wide Li-ion insertion channels.

Electrode Materials for Lithium Ion Batteries

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries (LIBs) have been widely adopted as the most promising portable energy source in electronic devices because of their high working voltage, high energy density, and good cyclic performance.

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