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740810

Sigma-Aldrich

2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid pentafluorophenyl ester

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About This Item

Formula empirica (notazione di Hill):
C23H31F5O2S3
Numero CAS:
1174764-26-1
Peso molecolare:
530.68
Numero MDL:
MFCD22417193
Codice UNSPSC:
12352100
ID PubChem:
329765442
NACRES:
NA.23

Forma fisica

liquid

Impurezze

4-5% pentafluorophenol

Indice di rifrazione

n20/D 1.512

Densità

1.203 g/mL at 25 °C

Temperatura di conservazione

2-8°C

Stringa SMILE

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C23H31F5O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-32-22(31)33-23(2,3)21(29)30-20-18(27)16(25)15(24)17(26)19(20)28/h4-14H2,1-3H3
XBUCQRRMAZYXHN-UHFFFAOYSA-N

Descrizione generale

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Applicazioni

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene; acrylate and acrylamide monomers. Chain Transfer Agent (CTA)

Altre note

The product contains 4-5% pentafluorophenol impurity. This impurity is typically not capable of interfering with the chain transfer agent

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articoli

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

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A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

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Protocolli

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

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Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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