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Key Documents

423742

Sigma-Aldrich

3,5-Dimethoxytoluene

98%

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About This Item

Formula condensata:
CH3C6H3(OCH3)2
Numero CAS:
Peso molecolare:
152.19
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Saggio

98%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.522 (lit.)

P. eboll.

244 °C (lit.)

Densità

1.039 g/mL at 25 °C (lit.)

Stringa SMILE

COc1cc(C)cc(OC)c1

InChI

1S/C9H12O2/c1-7-4-8(10-2)6-9(5-7)11-3/h4-6H,1-3H3
RIZBLVRXRWHLFA-UHFFFAOYSA-N

Descrizione generale

3,5-Dimethoxytoluene (DMT) is a methoxylated phenolic derivative. It is reported to be one of the main constituent of the floral volatiles in different rose varieties. It has been biosynthesized from orcinol by two successive methylation catalyzed by O-methyltransferases (OMTs). The features of its aerobic oxidation with metal/bromide catalysts have been investigated.

Applicazioni

3,5-Dimethoxytoluene (DMT) may be used in the synthesis of 3,5-dimethoxybenzoic acid by oxidation and 2-methoxy-6-methyl-1,4-benzoquinone by catalytic oxidation with hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3) in dimethyl carbonate (DMC).

Pittogrammi

Exclamation mark

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

215.6 °F - closed cup

Punto d’infiammabilità (°C)

102 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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The Unusual Characteristics of the Aerobic Oxidation of 3, 4-Dimethoxytoluene with Metal/Bromide Catalysts.
Partenheimer W.
Advanced Synthesis & Catalysis, 346(12), 1495-1500 (2004)
Studies in the biochemistry of micro-organisms: Synthesis of catenarin (1:4:5:7-tetrahydroxy-2-methylanthraquinone), a metabolic product of species of Helminthosporium.
W K Anslow et al.
The Biochemical journal, 35(8-9), 1006-1010 (1941-09-01)
Gabriel Scalliet et al.
Proceedings of the National Academy of Sciences of the United States of America, 105(15), 5927-5932 (2008-04-17)
The phenolic methyl ether 3,5-dimethoxytoluene (DMT) is a major scent compound of many modern rose varieties, and its fragrance participates in the characteristic "tea scent" that gave their name to Tea and Hybrid Tea roses. Among wild roses, phenolic methyl
Dimethyl carbonate: an environmentally friendly solvent for hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3, MTO) catalytic oxidations.
Bernini R, et al.
Tetrahedron, 63(29), 6895-6900 (2007)
Feng Zhang et al.
Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 29(5), 411-413 (2005-02-15)
To establish a method for GC fingerprint determination of the chemical constituents in Herba Asari. GC and GC-MS were used to optimize the fingerprint determination method, and identify the main peaks in the GC fingerprint. A preferable method for GC

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