423742
3,5-Dimethoxytoluene
98%
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About This Item
Prodotti consigliati
Saggio
98%
Forma fisica
liquid
Indice di rifrazione
n20/D 1.522 (lit.)
P. eboll.
244 °C (lit.)
Densità
1.039 g/mL at 25 °C (lit.)
Stringa SMILE
COc1cc(C)cc(OC)c1
InChI
1S/C9H12O2/c1-7-4-8(10-2)6-9(5-7)11-3/h4-6H,1-3H3
RIZBLVRXRWHLFA-UHFFFAOYSA-N
Descrizione generale
3,5-Dimethoxytoluene (DMT) is a methoxylated phenolic derivative. It is reported to be one of the main constituent of the floral volatiles in different rose varieties. It has been biosynthesized from orcinol by two successive methylation catalyzed by O-methyltransferases (OMTs). The features of its aerobic oxidation with metal/bromide catalysts have been investigated.
Applicazioni
3,5-Dimethoxytoluene (DMT) may be used in the synthesis of 3,5-dimethoxybenzoic acid by oxidation and 2-methoxy-6-methyl-1,4-benzoquinone by catalytic oxidation with hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3) in dimethyl carbonate (DMC).
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
10 - Combustible liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
215.6 °F - closed cup
Punto d’infiammabilità (°C)
102 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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The Unusual Characteristics of the Aerobic Oxidation of 3, 4-Dimethoxytoluene with Metal/Bromide Catalysts.
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The Biochemical journal, 35(8-9), 1006-1010 (1941-09-01)
Proceedings of the National Academy of Sciences of the United States of America, 105(15), 5927-5932 (2008-04-17)
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Dimethyl carbonate: an environmentally friendly solvent for hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3, MTO) catalytic oxidations.
Tetrahedron, 63(29), 6895-6900 (2007)
Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 29(5), 411-413 (2005-02-15)
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