187240
9-Anthracenemethanol
97%
Sinonimo/i:
9-(Hydroxymethyl)anthracene
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About This Item
Formula empirica (notazione di Hill):
C15H12O
Numero CAS:
Peso molecolare:
208.26
Beilstein:
1873402
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Saggio
97%
Solubilità
chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow
Gruppo funzionale
hydroxyl
Stringa SMILE
OCc1c2ccccc2cc3ccccc13
InChI
1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
JCJNNHDZTLRSGN-UHFFFAOYSA-N
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Categorie correlate
Descrizione generale
9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide.
9-Anthracenemethanol is a derivative of anthracene used in the Diels-Alder reactions.
9-Anthracenemethanol is a derivative of anthracene used in the Diels-Alder reactions.
Applicazioni
9-Anthracenemethanol can be used:
- As a starting material to prepare 9-anthracenylmethyl-1-piperazinecarboxylate, which acts as a reagent in the determination of isocyanates using HPLC.
- In the Diels-Alder reaction with dimethylacetylene-dicarboxylate to yield lactone derivatives.
- As an initiator in the ring-opening polymerization of δ-valerolactone to yield poly(δ-valerolactone).
- As a starting material in the synthesis of polymer-supported anthracene, which acts as a dienophile scavenger in cycloaddition reactions.
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
Eyeshields, Gloves, type N95 (US)
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Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
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Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 96, 768-775 (2012-08-14)
Vibrational spectral measurements were made for 9-anthracenemethanol. Optimized geometrical structure and harmonic vibration frequencies were computed based on ab initio and density functional theory B3LYP methods using 6-311G(**) and LANL2DZ basis sets. The equilibrium geometries got from all of the
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This paper proposes a one-step method for preparation of fluorescent 9-anthrylmethyl esters from triacylglycerols (TAG) ranging in amount from 0.1 to 5 microg. It involves base-catalyzed transesterification using potassium 9-anthracenemethoxide, prepared by proton exchange between 9-anthracenemethanol and potassium tert-butoxide. Transesterification
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