167398
tert-Butyl carbamate
98%
Sinonimo/i:
Boc-amide
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About This Item
Formula condensata:
NH2COOC(CH3)3
Numero CAS:
Peso molecolare:
117.15
Beilstein:
1744500
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Livello qualitativo
Saggio
98%
Forma fisica
solid
Punto di fusione
105-108 °C (lit.)
Stringa SMILE
CC(C)(C)OC(N)=O
InChI
1S/C5H11NO2/c1-5(2,3)8-4(6)7/h1-3H3,(H2,6,7)
LFKDJXLFVYVEFG-UHFFFAOYSA-N
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Descrizione generale
Palladium-catalyzed cross-coupling reaction of tert-butyl carbamate with various aryl(Het) halides with Cs2CO3 as base in 1,4-dioxane (solvent) has been investigated.
Applicazioni
tert-Butyl carbamate was used in palladium-catalyzed synthesis of N-Boc-protected anilines. It was used in the synthesis of tetrasubstituted pyrroles, functionalized with ester or ketone groups at C-3 position.
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
Eyeshields, Gloves, type N95 (US)
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The Journal of organic chemistry, 74(12), 4634-4637 (2009-06-13)
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