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126632

Sigma-Aldrich

1,2-Dinitrobenzene

97%

Sinonimo/i:

o-Dinitrobenzene

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About This Item

Formula condensata:
C6H4(NO2)2
Numero CAS:
528-29-0
Peso molecolare:
168.11
Beilstein:
642224
Numero CE:
208-431-8
Numero MDL:
MFCD00007093
Codice UNSPSC:
12352100
ID PubChem:
24847736
NACRES:
NA.22

Livello qualitativo

100

Saggio

97%

Stato

solid

P. ebollizione

319 °C/773 mmHg (lit.)

Punto di fusione

114-117 °C (lit.)

Gruppo funzionale

nitro

Stringa SMILE

[O-][N+](=O)c1ccccc1[N+]([O-])=O

InChI

1S/C6H4N2O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H
IZUKQUVSCNEFMJ-UHFFFAOYSA-N

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Descrizione generale

1,2-Dinitrobenzene (o-Dinitrobenzene) is one of the nitroaromatic compounds present in urine which has been studied using gas chromatography-mass spectrometry-selected ion monitoring methods†. The electrochemistry of 1,2-dinitrobenzene (o-Dinitrobenzene) is strongly affected by 1,3-diphenylurea.

Applicazioni

  • A highly divergent Pictet-Spengler approach for pyrrolo quinoxalines from aryl amine using 1,2-dinitrobenzene as an oxidant: Discusses the utility of 1,2-dinitrobenzene as an oxidant in organic synthesis, relevant for developing novel pharmaceuticals (Pardeshi et al., 2019).

Avvertenze

Danger

Indicazioni di pericolo

H300 + H310 + H330,H373,H410

Classi di pericolo

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

302.0 °F - closed cup

Punto d’infiammabilità (°C)

150 °C - closed cup

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Certificati d'analisi (COA)

Lot/Batch Number
STBK9056
STBK7073
STBK0017
STBH8832
STBH3032

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Cindy Chan-Leonor et al.
The Journal of organic chemistry, 70(26), 10817-10822 (2005-12-17)
[reaction: see text] The electrochemistry of 1,2-dinitrobenzene (1,2-DNB), 1,3-dinitrobenzene (1,3-DNB), and 1,4-dinitrobenzene (1,4-DNB) is strongly affected by the presence of 1,3-diphenylurea. In DMF, the second reduction potential of all three DNBs shifts substantially positive in the presence of the urea
D Mahadevan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 84(1), 86-98 (2011-10-14)
In this work, the comparative analysis is made on the structure and vibrational spectra of 1,2-Dinitro benzene (1,2-DNB) and 1-Fluoro-3-nitro benzene (1-F-3-NB) molecules. The FT-IR and FT-Raman experimental spectra of the molecules have been recorded using Bruker IFS 66 V
P A Cossum et al.
Drug metabolism and disposition: the biological fate of chemicals, 13(6), 664-668 (1985-11-01)
The metabolism of radiolabeled dinitrobenzene (DNB) isomers was compared in hepatocytes and hepatic subcellular fractions isolated from male Fischer-344 rats. Under aerobic conditions, reduction was the major metabolic pathway for m- and p- DNB in hepatocytes with m- and p-nitroaniline
H Tamaki et al.
Journal of bacteriology, 181(9), 2958-2962 (1999-04-28)
Glutathione S-transferases (GSTs) Y-1 and Y-2 from the yeast Issatchenkia orientalis were purified by passage through a glutathione-agarose column, and the cDNA for GST Y-1 was cloned and sequenced. The deduced amino acid sequence consisted of 188 residues with a
J V Barbo et al.
Journal of immunology (Baltimore, Md. : 1950), 154(4), 1551-1559 (1995-02-15)
A population of CD8+ T cells from dinitrobenzene sulfonate-primed mice produce soluble effector molecules that down-regulate the magnitude of dinitrophenol-specific contact hypersensitivity reactions. These soluble molecules express the binding specificity and serologic determinants of alpha/beta TCR. To examine the requirement
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