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379832

Sigma-Aldrich

Potassium sodium tartrate tetrahydrate

99.98% trace metals basis

Synonym(s):

L(+)-Tartaric acid potassium Sodium salt, Rochelle salt, Seignette salt

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About This Item

Linear Formula:
KOCOCH(OH)CH(OH)COONa · 4H2O
CAS Number:
Molecular Weight:
282.22
Beilstein:
6113568
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

Quality Level

Assay

99.98% trace metals basis

form

solid

SMILES string

O.O.O.O.[Na+].[K+].O[C@H]([C@@H](O)C([O-])=O)C([O-])=O

InChI

1S/C4H6O6.K.Na.4H2O/c5-1(3(7)8)2(6)4(9)10;;;;;;/h1-2,5-6H,(H,7,8)(H,9,10);;;4*1H2/q;2*+1;;;;/p-2/t1-,2-;;;;;;/m1....../s1

InChI key

VZOPRCCTKLAGPN-ZFJVMAEJSA-L

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General description

Potassium sodium tartrate tetrahydrate, commonly called as Rochelle salt, is a ferroelectric crystal with high piezoelectric effect. It is deliquescent and water soluble with highest electromechanical coupling coefficient. It is a component of DNS (3,5-dinitrosalicylic acid) reagent, a colorimetric reagent and Fehling′s solution B which are used in the determination of reducing sugar. NMR spectra and the spin-lattice relaxation times has been reported.

Application

Potassium sodium tartrate tetrahydrate may be used in the following processes:
  • Polyphenol assay.
  • Synthesis of iron nanoparticles, whcih are used in the synthesis of amorphous carbon nanofibers.
  • As a component in the reservoir solution used to induce crystallization of proteins.
  • As a component of aqueous plating solution for electroless silver deposition on polycarbonate substrates.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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New ferroelastic properties and the paraelectric-ferroelectric-paraelectric phase transitions of Rochelle salt.
Lim AR and Lee KS.
Journal of Applied Physics, 110(3), 033520-033520 (2011)
Scott Reiling et al.
Acta crystallographica. Section F, Structural biology communications, 70(Pt 11), 1485-1491 (2014-11-06)
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Ligand-optimized electroless synthesis of silver nanotubes and their activity in the reduction of 4-nitrophenol.
Muench F, et al.
Nanotechnology, 22(41), 415602-415602 (2011)
Jan T, et al.
Fundamentals of Piezoelectric Sensorics: Mechanical, Dielectric, and Thermodynamical Properties of Piezoelectric Materials, 11-11 (2010)

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