464872

Lithium diphenylphosphide solution

0.5 M in THF

• Synonym(s): Diphenyl lithium phosphide, Diphenylphosphine lithium salt, Diphenylphosphino)lithium, Lithiodiphenyl phosphide, Lithiodiphenylphosphine
• Linear Formula: (C₆H₅)₂PLi
• CAS Number: 65567-06-8
• Molecular Weight: 192.12
• MDL number: MFCD00046054
• UNSPSC Code: 12352002
• PubChem Substance ID: 24870228
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• concentration: 0.5 M in THF
• bp: 65-67 °C
• density: 0.925 g/mL at 25 °C
• SMILES string: [Li]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H10P.Li/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
• InChI key: WKUYEGHEUWHKIU-UHFFFAOYSA-N

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H225,H302 + H332,H314,H335,H351,H410
• Precautionary Statements: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): -4.0 °F - closed cup
• Flash Point(C): -20 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves