425508

2,6-Dimethylphenylmagnesium bromide solution

1.0 M in THF

• Synonym(s): 2,6-Xylylmagnesium bromide, Bromo(2,6-dimethylphenyl)magnesium
• Linear Formula: (CH₃)₂C₆H₃MgBr
• CAS Number: 21450-64-6
• Molecular Weight: 209.37
• MDL number: MFCD00192083
• UNSPSC Code: 12352103
• PubChem Substance ID: 24866639
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• concentration: 1.0 M in THF
• bp: 65-67 °C
• density: 0.998 g/mL at 25 °C
• SMILES string: Cc1cccc(C)c1[Mg]Br
• InChI: 1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
• InChI key: BIGUVDUZGAJWQK-UHFFFAOYSA-M

Description

Application

2,6-Dimethylphenylmagnesium bromide can be used:

• As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
• As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS05
• Signal Word: Danger
• Hazard Statements: H225,H261,H302,H314,H331,H335,H351
• Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): -2.2 °F - closed cup
• Flash Point(C): -19 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves