339237
Zirconium(IV) isopropoxide isopropanol complex
99.9% trace metals basis
Synonym(s):
Propan-2-ol propan-2-olate zirconium(4+), Zirconium (2-propanol)tetrakis(2-propanolato)
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About This Item
Linear Formula:
Zr(OCH(CH3)2)4 · (CH3)2CHOH
CAS Number:
Molecular Weight:
387.67
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99.9% trace metals basis
form
powder
reaction suitability
core: zirconium
SMILES string
CC(C)O.CC(C)O[Zr](OC(C)C)(OC(C)C)OC(C)C
InChI
1S/C3H8O.4C3H7O.Zr/c5*1-3(2)4;/h3-4H,1-2H3;4*3H,1-2H3;/q;4*-1;+4
InChI key
NIJDLRJGRCHJDB-UHFFFAOYSA-N
Related Categories
Application
Convenient precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.
Zirconium(IV) isopropoxide isopropanol complex may be used as a precursor to ZrO2.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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William J. Evans et al.
Inorganic chemistry, 38(6), 1160-1164 (2001-10-24)
The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three crystallographically characterizable complexes isolable in 55-90% yield are reported. Eugenol, HOC(6)H(3)(OMe-2)(CH(2)CH=CH(2)-4) (HOAr) reacts with [Zr(O(i)Pr)(4)(HO(i)Pr)](2)
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