798371
Exo-Phenyl Kwon [2.2.1] Bicyclic Phosphine
95% (HPLC)
Synonym(s):
(1S,4S,5R)-5-(phenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
About This Item
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Quality Level
Assay
95% (HPLC)
form
powder
storage condition
under inert gas
mp
158-162 °C
storage temp.
2-8°C
SMILES string
CC1=CC=C(S(N2C[C@@]3([H])[P@](C4=CC=CC=C4)C[C@]2([H])C3)(=O)=O)C=C1
InChI
1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3
InChI key
BWXYDSDVFPJTFY-UHFFFAOYSA-N
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Related Categories
Application
Other Notes
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Chiral phosphines have been the staple ligands for asymmetric transition metal catalysis and more recently operate as catalysts in organic phosphinocatalysis.
Related Content
The Kwon Group has made major strides in the development and application of nucleophilic phosphinocatalysis reactions as a means to synthesize carbo- and heterocycles that serve as synthetic intermediates for both natural products and medicinally useful compounds.
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