774448

4-Chlorophenylmagnesium bromide solution

1.0 M in 2-methyltetrahydrofuran

• Synonym(s): (4-Chlorophenyl)magnesium bromide, p-Chlorophenylmagnesium bromide
• Linear Formula: ClC₆H₄MgBr
• CAS Number: 873-77-8
• Molecular Weight: 215.76
• MDL number: MFCD00009926
• UNSPSC Code: 12352103
• PubChem Substance ID: 329767685
• NACRES: NA.22

Properties

• form: solution
• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• concentration: 1.0 M in 2-methyltetrahydrofuran
• density: 1.005 g/mL at 25 °C
• greener alternative category: Aligned,
• storage temp.: 2-8°C
• SMILES string: Clc1ccc([Mg]Br)cc1
• InChI: 1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1
• InChI key: CDEMHJCJMMOFMB-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Find details here.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• Pictograms: GHS02,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225 - H302 - H314
• Precautionary Statements: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Supplementary Hazards: EUH014 - EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 8.6 °F - closed cup
• Flash Point(C): -13.0 °C - closed cup