All Photos(1)

Key Documents

687596

(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Name: (11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide
Brand: ALDRICH

Nagase purity

Sign Into View Organizational & Contract Pricing

All Photos(1)

About This Item

Empirical Formula (Hill Notation):

C₄₂H₃₆BrF₆N

CAS Number:

887938-70-7

Molecular Weight:

748.64

MDL number:

MFCD09264271

UNSPSC Code:

12352005

PubChem Substance ID:

329761140

NACRES:

NA.22

Recommended Products

Slide 1 of 10

1 of 10

Sigma-Aldrich

499617

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

Sigma-Aldrich

677086

(11bS)-(+)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Sigma-Aldrich

524433

N-Benzylcinchonidinium bromide

Sigma-Aldrich

C9322

Catalase from bovine liver

Sigma-Aldrich

669997

Δ-TRISPHAT tetrabutylammonium salt

Sigma-Aldrich

323764

1,1′-Diethyl-2,2′-cyanine iodide

Sigma-Aldrich

374482

N-Benzylquininium chloride

Sigma-Aldrich

719838

1-Bromo-2,6-diisopropylbenzene

Sigma-Aldrich

364002

(1S,2S)-(−)-1,2-Diphenylethylenediamine

Sigma-Aldrich

A8674

Antimycin A from Streptomyces sp.

Quality Level

100

form

solid

mp

223-228 °C

functional group

fluoro

SMILES string

CCCC[N+]1(CCCC)Cc2c(cc3ccccc3c2-c4c(C1)c(cc5ccccc45)-c6cc(F)c(F)c(F)c6)-c7cc(F)c(F)c(F)c7

InChI

1S/C42H36F6N.BrH/c1-3-5-15-49(16-6-4-2)23-33-31(27-19-35(43)41(47)36(44)20-27)17-25-11-7-9-13-29(25)39(33)40-30-14-10-8-12-26(30)18-32(34(40)24-49)28-21-37(45)42(48)38(46)22-28;/h7-14,17-22H,3-6,15-16,23-24H2,1-2H3;1H/q+1;/p-1

InChI key

LOMUZNOWQYZTRP-UHFFFAOYSA-M

Application

Potent phase transfer organocatalyst for asymmetric α-alkylation of glycine derivatives at extremely low loadings.

Features and Benefits

Maruoka phase-transfer catalysts are:

Operationally straightforward
Environmentally friendly
Relatively mild reaction conditions
Reactions conducted in aqueous media
Low catalyst loading

Legal Information

Product of Nagase & Co. Ltd.

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Organocatalysis

Aldrich Chemfiles, 7(9), 19-19 (2007)

Kitamura, M. et al.

Tetrahedron Asymmetry, 17, 603-603 (2006)

Articles

Maruoka Catalysts

Asymmetric phase transfer catalysis using the Maruoka catalysts has proven to be an ideal method for the enantioselective preparation of natural and unnatural α-alkyl and α,α-dialkyl-α-amino acids from glycine derivati

Key Documents

(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Nagase purity

About This Item

Recommended Products

Properties

Quality Level

form

mp

functional group

SMILES string

InChI

InChI key

Description

Application

Features and Benefits

Legal Information

Safety Information

Pictograms

Signal Word

Hazard Statements

Precautionary Statements

Hazard Classifications

Target Organs

Storage Class Code

WGK

Flash Point(F)

Flash Point(C)

Documentation

Certificates of Analysis (COA)

Already Own This Product?

Peer Reviewed Papers

Protocols and Articles

Articles

Related Content

Technical Service