256021

(Trimethylsilyl)methylmagnesium chloride solution

1.0 M in diethyl ether

• Synonym(s): (Trimethylsilyl)methyl magnesium chloride, Chloro(trimethylsilylmethyl)magnesium
• Linear Formula: (CH₃)₃SiCH₂MgCl
• CAS Number: 13170-43-9
• Molecular Weight: 146.97
• Beilstein: 3587255
• MDL number: MFCD00009916
• UNSPSC Code: 12352103
• PubChem Substance ID: 24855503
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• concentration: 1.0 M in diethyl ether
• density: 0.777 g/mL at 25 °C
• SMILES string: C[Si](C)(C)C[Mg]Cl
• InChI: 1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1
• InChI key: NAQATMJWCJCHOZ-UHFFFAOYSA-M

Description

Application

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Safety Information

• Pictograms: GHS02,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H314,H336
• Precautionary Statements: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Central nervous system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): -40.0 °F - closed cup
• Flash Point(C): -40 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves