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Azinphos-methyl-(dimethyl-d6)

PESTANAL®, analytical standard

Synonym(s):

Azinphos-methyl-d6, Methyltriazotin-d6

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About This Item

Empirical Formula (Hill Notation):
C10D6H6N3O3PS2
Molecular Weight:
323.36
MDL number:
MFCD03701752
UNSPSC Code:
12352200
PubChem Substance ID:
329769564
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture

format

neat

storage temp.

2-8°C

SMILES string

O=C1N(CSP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)N=NC2=CC=CC=C21

InChI

1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3/i1D3,2D3

InChI key

CJJOSEISRRTUQB-WFGJKAKNSA-N

Related Categories

General description

Azinphos-methyl-(dimethyl-d6) is an isotope-labeled analog of the organophosphorus anticholinesterase insecticide azinphos-methyl, wherein dimethoxy protons are substituted by deuterium.

Application

Azinphos-methyl-(dimethyl-d6) may be used as a deuterated internal standard to determine the levels of pesticide analytes in foods, fruits and vegetable matrices by gas chromatography (GC) based techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF5823
BCBZ4934
BCBR5914V
BCBR5914

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Combined use of a modifier gas generator, analyte protectants and multiple internal standards for effective and robust compensation of matrix effects in gas chromatographic analysis of pesticides
Tsuchiyama T, et al.
Journal of Chromatography A, 1589(3), 122-133 (2019)
Effects of carbaryl and azinphos methyl on juvenile rainbow trout (Oncorhynchus mykiss) detoxifying enzymes
Ferrari A, et al.
Pesticide Biochemistry and Physiology, 88(2), 134-142 (2007)
Ali Özcan et al.
Water research, 47(3), 1470-1479 (2013-01-02)
The removal of organophosphorous insecticide azinphos-methyl (AZPM) from water has been investigated by the electro-Fenton method which produces hydroxyl radicals electro-catalytically. The reaction between these radicals and AZPM has led to the oxidation of AZPM up to carbon dioxide and

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