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Key Documents

T83607

Sigma-Aldrich

Bromotriphenylmethane

98%

Synonym(s):

Triphenylbromomethane, Trityl bromide

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About This Item

Linear Formula:
(C6H5)3CBr
CAS Number:
Molecular Weight:
323.23
Beilstein:
1878494
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

bp

230 °C/15 mmHg (lit.)

mp

152-154 °C (lit.)

storage temp.

2-8°C

SMILES string

BrC(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H15Br/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

NZHXEWZGTQSYJM-UHFFFAOYSA-N

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Application

Reagent for the preparation of trityl esters.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Siddabasave Gowda B Gowda et al.
Lipids, 55(4), 395-401 (2020-05-15)
An efficient three-step strategy for the convenient synthesis of Sn-glycero-3-phosphoethanolamine (GroPEtn) from a commercially available 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine (DPPE) is reported. Direct hydrolysis of DPPE produces a complex inseparable mixture, hence a protection and deprotection strategy is employed to prepare GroPEtn. The
Cansu Aydogan et al.
Macromolecular rapid communications, 40(14), e1900109-e1900109 (2019-05-16)
A straightforward transformation protocol combining two distinct living polymerization methods for the controlled synthesis of block copolymers is described. In the first step, bromo-terminated poly(methyl methacrylate) is prepared by atom transfer radical polymerization (ATRP). Then, a bromide end group is
Krzysztof Matyjaszewski et al.
Molecules (Basel, Switzerland), 26(2) (2021-01-14)
N-alkyl phosphoranimines were synthesized via the Staudinger reaction of four different alkyl azides with tris(2,2,2-trifluoroethyl) phosphite. N-adamantyl, N-benzyl, N-t-butyl, and N-trityl phosphoranimines were thoroughly characterized and evaluated as chain-capping compounds in the anionic polymerization of P-tris(2,2,2-trifluoroethoxy)-N-trimethylsilyl phosphoranimine monomer. All four
Salvatore Debonis et al.
Journal of medicinal chemistry, 51(5), 1115-1125 (2008-02-13)
The human kinesin Eg5 is a potential drug target for cancer chemotherapy. Eg5 specific inhibitors cause cells to block in mitosis with a characteristic monoastral spindle phenotype. Prolonged metaphase block eventually leads to apoptotic cell death. S-trityl-L-cysteine (STLC) is a

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