907111
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide
Synonym(s):
(bpp)NiBr2
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About This Item
Empirical Formula (Hill Notation):
C11H9Br2N5Ni
CAS Number:
Molecular Weight:
429.72
UNSPSC Code:
12352101
NACRES:
NA.22
Recommended Products
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
Precatalyst for alkyl-alkyl cross-coupling; reductive cross-coupling of styrenyl aziridines, dialkyl ether formation, reductive amination.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Christoph Heinz et al.
Journal of the American Chemical Society, 140(6), 2292-2300 (2018-01-18)
This report describes a three-component, Ni-catalyzed reductive coupling that enables the convergent synthesis of tertiary benzhydryl amines, which are challenging to access by traditional reductive amination methodologies. The reaction makes use of iminium ions generated in situ from the condensation
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