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307874

Sigma-Aldrich

Scandium(III) oxide

99.9% trace rare earth metals basis

Synonym(s):

Discandium trioxide, Scandia, Scandium oxide, Scandium trioxide

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About This Item

Linear Formula:
Sc2O3
CAS Number:
12060-08-1
Molecular Weight:
137.91
EC Number:
235-042-0
MDL number:
MFCD00011223
UNSPSC Code:
12161600
PubChem Substance ID:
24858634
NACRES:
NA.22

Assay

99.9% trace rare earth metals basis

form

powder

reaction suitability

core: scandium
reagent type: catalyst

SMILES string

O=[Sc]O[Sc]=O

InChI

1S/3O.2Sc

InChI key

HYXGAEYDKFCVMU-UHFFFAOYSA-N

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General description

Scandium(III) oxide is a high-melting rare earth oxide that can be used as a catalyst in the dehydration of terminal diols. Furthermore, it is used as a starting material for the preparation of other scandium compounds.

Application

Scandium(III) oxide can be used as a catalyst for the dehydration of amino alcohols to unsaturated amines. It can also be used as a precursor to prepare scandium(III) trifluoromethanesulfonate, which can be used to catalyze the nitration of aromatic compounds.
Suitable for vacuum deposition applications

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ5205
MKCP6294
MKCN9392
MKCM2856
MKCJ3912

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Dehydration of 5-amino-1-pentanol over rare earth oxides
Ohta K, et al.
Applied Catalysis A: General, 517, 73-80 (2016)
Yan-Xia Zhao et al.
Physical chemistry chemical physics : PCCP, 13(21), 10084-10090 (2011-04-28)
The Sc(3)O(6)(-) cluster anions were produced by laser ablation and studied by reaction with n-butane in a fast flow reactor and by photoelectron spectroscopy. The reactivity experiments indicated that one Sc(3)O(6)(-) cluster can activate two n-butane molecules consecutively with rate
[Industrial hygiene in scandium oxide manufacture].
B G Feĭgin
Gigiena truda i professional'nye zabolevaniia, (4)(4), 39-40 (1985-04-01)
H M T U Herath et al.
Journal of materials science. Materials in medicine, 16(11), 1061-1065 (2006-01-03)
Biocompatibility is a pre-requisite for all biomaterials used for medical application. During the last two decades significant advances have been made in the development of novel materials and selection and use of these materials has been directly dependent upon their
Yu Gong et al.
The journal of physical chemistry. A, 111(45), 11572-11578 (2007-10-18)
The reactions of scandium atoms and O(2) have been reinvestigated using matrix isolation infrared spectroscopy and density functional theory calculations. A series of new oxygen-rich scandium oxide/dioxygen complexes were prepared and characterized. The ground state scandium atoms react with dioxygen
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