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Sigma-Aldrich

Hexaammineruthenium(III) chloride

98%

Synonym(s):

Hexaammineruthenium trichloride

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About This Item

Linear Formula:
[Ru(NH3)6]Cl3
CAS Number:
14282-91-8
Molecular Weight:
309.61
EC Number:
238-176-8
MDL number:
MFCD00011478
UNSPSC Code:
12161600
PubChem Substance ID:
24855851
NACRES:
NA.22

Quality Level

100

Assay

98%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

storage temp.

2-8°C

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Ru+3]

InChI

1S/3ClH.6H3N.Ru/h3*1H;6*1H3;/q;;;;;;;;;+3/p-3

InChI key

GBDZMMXUOBAJMN-UHFFFAOYSA-K

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General description

Hexaammineruthenium III/II (HexRu(III)|HexRu(II)) couple is a commonly used electrochemical redox couple due to its chemical and electrochemical reversibility.

Application

Hexaammineruthenium(III) chloride can be used as a precursor for the preparation of:
  • Ru/Al2O3 catalyst for CO2 hydrogenation.
  • Bimetallic complexes ([Ru(NH3)6][Ag(CN)2]3·2H2O).
  • Chloropentaammineruthenium(III) chloride.
For small scale and high throughput uses, product is also available as ChemBeads (932183)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Juan Yao et al.
The Analyst, 142(21), 4116-4123 (2017-10-11)
An isothermal, enzyme free, ultra-specific and ultra-sensitive protocol for electrochemical detection of miRNAs is proposed based on the toehold-mediated strand displacement reaction (SDR) and non-enzymatic catalytic hairpin reaction (CHA) recycling. The SDR was first triggered only in the presence of
Measurement of the diffusion coefficients of [Ru (NH3) 6] 3+ and [Ru (NH3) 6] 2+ in aqueous solution using microelectrode double potential step chronoamperometry.
Wang Y, et al,
Journal of Electroanalytical Chemistry, 652(1-2), 13-17 (2011)
Qian Yang et al.
Nanoscale, 9(46), 18523-18528 (2017-11-23)
A molecular check valve is a nanomachine that enables unidirectional molecular transport. In this work, we report a novel molecular check valve fabricated by asymmetric modification of a silica nanoporous membrane (SNM) consisting of parallel nanochannels with a diameter of
Daniel Martín-Yerga et al.
Analytica chimica acta, 981, 24-33 (2017-07-12)
In this work, we report a simple and yet efficient stencil-printed electrochemical platform that can be integrated into the caps of sample containers and thus, allows in-field quantification of Cd(II) and Pb(II) in river water samples. The device exploits the
Binuclear complexes of ruthenium ammines.
Creutz C and Taube H
Journal of the American Chemical Society, 95(4), 1086-1094 (1973)
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