235016
Dimethylphenylsilane
≥98%
Synonym(s):
Phenyldimethylsilane
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About This Item
Linear Formula:
C6H5SiH(CH3)2
CAS Number:
Molecular Weight:
136.27
Beilstein:
2204906
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
≥98%
form
liquid
refractive index
n20/D 1.497 (lit.)
bp
157 °C/744 mmHg (lit.)
density
0.889 g/mL at 25 °C (lit.)
SMILES string
C[SiH](C)c1ccccc1
InChI
1S/C8H12Si/c1-9(2)8-6-4-3-5-7-8/h3-7,9H,1-2H3
InChI key
ZISUALSZTAEPJH-UHFFFAOYSA-N
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General description
Dimethylphenylsilane is used as a silylating agent in homocoupling reactions to produce well defined polymers.
Application
Reagent for enol ether synthesis.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
95.0 °F
Flash Point(C)
35 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained
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