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233595

Sigma-Aldrich

2,6-Diphenylphenol

98%

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About This Item

Linear Formula:
(C6H5)2C6H3OH
CAS Number:
2432-11-3
Molecular Weight:
246.30
EC Number:
219-401-9
MDL number:
MFCD00009716
UNSPSC Code:
12352100
PubChem Substance ID:
24853986
NACRES:
NA.22

Assay

98%

form

solid

mp

101-103 °C (lit.)

SMILES string

Oc1c(cccc1-c2ccccc2)-c3ccccc3

InChI

1S/C18H14O/c19-18-16(14-8-3-1-4-9-14)12-7-13-17(18)15-10-5-2-6-11-15/h1-13,19H

InChI key

ATGFTMUSEPZNJD-UHFFFAOYSA-N

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General description

2,6-Diphenylphenol reacts with with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene to yield the solvent-free complexes [M(OAr)]x.

Application

2,6-Diphenylphenol has been used:
  • as ligand during the synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systems
  • in the preparation of derivatives of pyrazine-2,3-dicarbonitrile, precursor required for the synthesis of octaazaphthalocyanine (AzaPc) derivatives

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Saad Makhseed et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(16), 4810-4815 (2008-05-01)
The synthesis of octaazaphthalocyanine (AzaPc) derivatives, with bulky phenoxyl substituents placed at eight peripheral positions and containing either H(+), Ni(2+) or Zn(2+) ions in their central cavity, is described. The required precursors, derivatives of pyrazine-2,3-dicarbonitrile, were prepared using a nucleophilic
Charles S Weinert et al.
Inorganic chemistry, 42(19), 6089-6094 (2003-09-16)
Reaction of 2,6-diphenylphenol (HOC(6)H(3)Ph(2)-2,6) with (n)BuLi, NaH, KH, or Rb or Cs metal in benzene gives the solvent-free complexes [M(OAr)]x in excellent yield. The complex [Rb(OC(6)H(3)Ph(2)-2,6)](x)() exhibits a ladderlike structure in the solid state with triply bridging oxygen atoms and
Sandeep K Kondaveeti et al.
Inorganic chemistry, 51(19), 10095-10104 (2012-09-06)
The synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systems is described. Addition of phenols to Mn(NR(2))(2) (R = SiMe(3)) results in protolytic amide ligand replacement, and represents the primary entry into the described chemistry. Addition of
Camilo J Viasus et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(68), 17269-17278 (2017-10-17)
The reactivity of carbon dioxide with vanadium(III) aryloxo complexes has been investigated. The formation of either carbon monoxide or incorporation into the ligand system with the ultimate formation of organic ester was observed depending on the overall electron donor ability
Ursula J Williams et al.
Dalton transactions (Cambridge, England : 2003), 43(43), 16197-16206 (2014-08-26)
The trivalent compound K[Ce[N(SiHMe2)2]4] was synthesized and oxidized, providing a convenient route to the reported cerium(IV) compound Ce[N(SiHMe2)2]4. Protonolysis reactions of Ce[N(SiHMe2)2]4 with tert-butanol, substituted benzyl alcohols, and 2,6-diphenylphenol yielded the neutral tetravalent compounds Ce(O(t)Bu)4(py)2, Ce2(OCH2C6R5)8(thf)2 (R = Me, F)

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