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Key Documents

225460

Sigma-Aldrich

Diironnonacarbonyl

98%

Synonym(s):

Enneacarbonyldiiron, Iron enneacarbonyl, Nonacarbonyldiiron

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About This Item

Linear Formula:
Fe2(CO)9
CAS Number:
Molecular Weight:
363.78
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

solid

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O

InChI

1S/9CO.2Fe/c9*1-2;;

InChI key

JCXLZXJCZPKTBW-UHFFFAOYSA-N

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Application

Reacts with phenylsilanes to give triply bridged diiron complexes.

Pictograms

FlameSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Gree, R.
Synthesis, 341-341 (1989)
Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Crump, S. L.; Netka, J.; Rickborn, B.
The Journal of Organic Chemistry, 50, 2746-2746 (1985)
Robert Ponec et al.
Journal of computational chemistry, 29(9), 1387-1398 (2008-01-16)
The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anticipated for

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