209058
Rhodium(II) acetate dimer
powder
Synonym(s):
Rh2(OAc)4, Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
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All Photos(3)
About This Item
Linear Formula:
Rh2(OOCCH3)4
CAS Number:
Molecular Weight:
441.99
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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form
powder
Quality Level
reaction suitability
core: rhodium
reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
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General description
Rhodium(II) acetate dimer is an effective catalyst for carbenoid reactions, hydrocarbon oxidation, hydroboration, and nitrene reactions.
Application
Effective catalyst for ylide formation.
Homogeneous catalyst.
Used in an efficient synthesis of ß-hydroxy-α-arylacrylates involving the decomposition of diazoetster intermediates with concomitant 1,2-arylmigration.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Carter, D.S. Van Vranken, D.L.
Tetrahedron Letters, 40, 1617-1617 (1999)
Aldrichimica Acta, 15, 13-13 (1982)
Tetrahedron Letters, 48, 1147-1147 (2007)
Doyle, M. P.
Chemical Reviews, 86, 919-919 (1986)
Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion.
Huw M L Davies et al.
Chemical reviews, 103(8), 2861-2904 (2003-08-14)
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