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139726

Sigma-Aldrich

Benzoyl bromide

97%

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About This Item

Linear Formula:
C6H5COBr
CAS Number:
618-32-6
Molecular Weight:
185.02
Beilstein:
1855439
EC Number:
210-544-2
MDL number:
MFCD00000112
UNSPSC Code:
12352100
PubChem Substance ID:
24848428
NACRES:
NA.22

Quality Level

200

Assay

97%

refractive index

n20/D 1.589 (lit.)

bp

218-219 °C (lit.)

density

1.57 g/mL at 25 °C (lit.)

SMILES string

BrC(=O)c1ccccc1

InChI

1S/C7H5BrO/c8-7(9)6-4-2-1-3-5-6/h1-5H

InChI key

AQIHMSVIAGNIDM-UHFFFAOYSA-N

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General description

Benzoyl bromide is a versatile reagent which causes the benzoylation of ethers.

Application

Benzoyl bromide was used to study the kinetics of solvolysis of benzoyl halides in microemulsions of sodium bis(2-ethylhexyl)sulfosuccinate/isooctane/water at 25°C.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335

Hazard Classifications

Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

194.0 °F - closed cup

Flash Point(C)

90 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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L García-Río et al.
Langmuir : the ACS journal of surfaces and colloids, 22(18), 7499-7506 (2006-08-23)
A study was carried out on the solvolysis reactions of different benzoyl halides in microemulsions of water/NH4DEHP/isooctane, where NH4DEHP is ammonium bis(2-ethylhexyl) phosphate. Because of the low solubility of benzoyl halides in water, they are distributed between the continuous medium
Tülay Polat et al.
Carbohydrate research, 338(5), 447-449 (2003-02-01)
A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and benzoylation by benzoyl bromide. In the same reaction, methyl or p-methoxyphenyl glycosides are
Mai Do et al.
Nanoscale, 11(37), 17262-17269 (2019-06-28)
Perovskite nanoparticles have attracted the attention of research groups around the world for their impressive photophysical properties, facile synthesis and versatile surface chemistry. Here, we report a synthetic route that takes advantage of a suite of soluble precursors to generate
Dmitry Baranov et al.
ACS nano, 15(1), 650-664 (2020-12-23)
Excitonic coupling, electronic coupling, and cooperative interactions in self-assembled lead halide perovskite nanocrystals were reported to give rise to a red-shifted collective emission peak with accelerated dynamics. Here we report that similar spectroscopic features could appear as a result of

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