CRM74120

Triazophos

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Empirical Formula (Hill Notation): C₁₂H₁₆N₃O₃PS
• CAS Number: 24017-47-8
• Molecular Weight: 313.31
• Beilstein: 682554
• MDL number: MFCD00055327
• UNSPSC Code: 41116107

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• storage temp.: −20°C
• SMILES string: CCOP(=S)(OCC)Oc1ncn(n1)-c2ccccc2
• InChI: 1S/C12H16N3O3PS/c1-3-16-19(20,17-4-2)18-12-13-10-15(14-12)11-8-6-5-7-9-11/h5-10H,3-4H2,1-2H3
• InChI key: AMFGTOFWMRQMEM-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Triazophos― a non-systemic insecticide and acaricide, is an acetylcholinesterase (AChE) inhibitor. An organophosphate, it covalently and irreversibly reacts with the acetylcholine binding site and blocks the hydrolysis of acetylcholine, resulting in hyper excitation. Its route of action includes both ingestion and contact. Triazophos is used against soil insects and mites such as aphids, thrips, midges, beetles, Lepidoptera larvae, cutworms, and spider mites in ornamentals, cotton, rice, maize, soybeans, oil palms, olives, and coffee.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, triazophos is not approved for use in the European Union as a plant protection agent. Maximum residue limits (MRLs) applied for the presence of triazophos in food products across different countries lie in the range of 0.01 to 0.2 mg/kg.
Triazophos has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Triazophos CRM may find the following uses:

• Analysis of a diagnostic method for the direct monitoring of triazophos by a non-competitive surface plasmon resonance immunosensor in environmental and agricultural product samples
• Simultaneous quantitative detection of 171 pesticide residues using multi-walled carbon nanotubes (MWCNTs) as a sorbent in the reversed-dispersive solid-phase (r-DSPE) extraction of the cowpea samples followed by gas chromatographic-tandem mass spectrometric (GC-MS/MS) analysis
• Development and validation of a multi-residue method for the analysis of 160 pesticides in herbal plants samples of chamomile, thyme, and marjoram using ethyl acetate and n-hexane mixture for the extraction before GC-MS/MS direct injection
• Determination of a wide group of 250 pesticide residues in surface water samples by solid-phase extraction (SPE) and reversed-phase liquid chromatography (LC)-Orbitrap high-resolution mass spectrometry (HRMS)
• Quantifying 126 pesticide residues in chicken muscle samples using QuEChERS for sample preparation and ultra-high-performance liquid chromatography- quadrupole time-of-flight-mass spectrometry (UHPLC-QToF-MS) for subsequent analysis

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H301 - H312 - H330 - H410
• Precautionary Statements: P260 - P264 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1
• Storage Class Code: 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable