210250
Hydroxylamine sulfate
99%
Synonym(s):
Hydroxylammonium sulfate
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About This Item
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Quality Level
Assay
99%
form
crystals
mp
170 °C (dec.) (lit.)
SMILES string
NO.NO.OS(O)(=O)=O
InChI
1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)
InChI key
VRXOQUOGDYKXFA-UHFFFAOYSA-N
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General description
Cyclohexanone oxime undergoes hydrolytic reaction with sulfuric acid to yield hydroxylamine sulfate. It reacts with sulfur dioxide to afford sulfamic acid.
Application
Hydroxylamine sulfate may be used in the following:
- Along with NaCl for reduction during the atomic absorption spectrophotometric quantification of mercury at ppb (parts-per-billion) levels in solution.
- As one of the constituents during the preparation of a coloring solution, impregnated in a cellulose based monitoring tape for the sensitive detection of formaldehyde gas.
- Simultaneous estimation of hydrarine and hydroxylamine in mixtures by titration with alkaline ferricyanide in presence of zinc sulfate.
Powerful reducing agent. Converts aldehydes and ketones to oximes, and acid chlorides to hydroxamic acids. Used as catalyst, swelling agent, and copolymerization inhibitor in polymerization processes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral
Target Organs
Blood
Storage Class Code
4.1A - Other explosive hazardous materials
WGK
WGK 3
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A simple and efficient approach for preparation of hydroxylamine sulfate from the acid-catalyzed hydrolysis reaction of cyclohexanone oxime.
Chemical Engineering Journal, 272, 102-107 (2015)
Determination of submicrogram quantities of mercury by atomic absorption spectrophotometry.
Analytical Chemistry, 40(14), 2085-2087 (1968)
The Preparation of Sulfamic Acid by the Hydroxylamine--Sulfur Dioxide Reaction.
Journal of the American Chemical Society, 61(12), 3389-3391 (1939)
Oxidation of hydroxylamine by ferricyanide in presence of zinc sulfate: A rapid method for estimating hydroxylamine and hydrazine in a mixture.
Analytica Chimica Acta, 20, 371-375 (1959)
Development of a monitoring tape for formaldehyde using hydroxylamine sulfate and methyl yellow.
Analytical Sciences, 10(4), 641-645 (1994)
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