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157740

Sigma-Aldrich

Iron(III) chloride

greener alternative

reagent grade, 97%

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Linear Formula:
FeCl3
CAS Number:
7705-08-0
Molecular Weight:
162.20
EC Number:
231-729-4
MDL number:
MFCD00011005
UNSPSC Code:
12352300
PubChem Substance ID:
329750852
NACRES:
NA.21

grade

reagent grade

Quality Level

200

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

Assay

97%

form

powder

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

304 °C (lit.)

greener alternative category

Aligned,

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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General description

Iron(III) chloride is a mild oxidizing agent and participates in various carbon-carbon-bond forming reactions. On crystallization with water, it forms hydrates. It can be prepared by reacting chlorine with the scrap iron at approximately 650°C.
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Application

Iron(III) chloride (Ferric Chloride, FeCl3) has been used as a surface modulator for the characterization of wines by fingerprinting technology. It has been used for the quantitative estimation of sulfide in various biological samples.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290 - H302 - H315 - H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class Code

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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"Iron (III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes"
Watahiki T, et al.
Organic Letters, 5(17), 3045-3048 (2003)
Novel non-specific liquid fingerprint technology for wine analysis: a feasibility study.
Siivonen JJ, et al.
Australian Journal of Grape and Wine Research, 20(2), 172-177 (2014)
"Iron (III) chloride-based mild synthesis of phenanthrene and its application to total synthesis of phenanthroindolizidine alkaloids"
Wang L-K, et al.
Tetrahedron, 64(32), 7504-7510 (2008)
Yuanyuan Kong et al.
Cell death & disease, 10(9), 624-624 (2019-08-20)
Recent findings demonstrate that aberrant downregulation of the iron-exporter protein, ferroportin (FPN1), is associated with poor prognosis and osteoclast differentiation in multiple myeloma (MM). Here, we show that FPN1 was downregulated in MM and that clustered regularly interspaced short palindromic
Mirjam Visscher et al.
Journal of the American Society for Mass Spectrometry, 30(9), 1790-1800 (2019-06-30)
Atherosclerosis is a lipid and inflammation-driven disease of the arteries that is characterized by gradual buildup of plaques in the vascular wall. A so-called vulnerable plaque, consisting of a lipid-rich necrotic core contained by a thin fibrous cap, may rupture
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