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T79758

Trimethyl phosphonoacetate

Name: Trimethyl phosphonoacetate
Brand: ALDRICH

98%

Synonym(s):

(Carboxymethyl)phosphonic acid trimethyl ester, NSC 84262

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About This Item

Linear Formula:

(CH₃O)₂P(O)CH₂CO₂CH₃

CAS Number:

5927-18-4

Molecular Weight:

182.11

Beilstein:

1865177

EC Number:

227-663-0

MDL number:

MFCD00008452

UNSPSC Code:

12352108

PubChem Substance ID:

24900489

NACRES:

NA.22

Assay

98%

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.437 (lit.)

bp

118 °C/0.85 mmHg (lit.)
265-268 °C (lit.)

density

1.125 g/mL at 25 °C (lit.)

SMILES string

COC(=O)CP(=O)(OC)OC

InChI

1S/C5H11O5P/c1-8-5(6)4-11(7,9-2)10-3/h4H2,1-3H3

InChI key

SIGOIUCRXKUEIG-UHFFFAOYSA-N

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Application

Reactant involved in:

Intramolecular Mannich-type reactions to produce the sarain A diazatricyclic core
Organocatalytic oxa-Michael reactions
Prenylation and geranylation of oxindoles
Intramolecular Horner-Wadsworth-Emmons reactions
Olefin cross-metathesis / heterocyclization

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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