ALD00006

Sodium bis(2-hydroxy-2-methylbutyrato)oxochromate(V)

• Synonym(s): 2-Hydroxy-2-methyl-butanoic acid chromium complex
• Empirical Formula (Hill Notation): C₁₀H₁₆CrNaO₇
• CAS Number: 66767-36-0
• Molecular Weight: 323.22
• UNSPSC Code: 12352005
• PubChem Substance ID: 329772512
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• mp: 340-350 °C
• SMILES string: [O-][Cr]1(O2)(OC(C(C)(CC)O1)=O)OC(C)(CC)C2=O.[Na+]
• InChI: 1S/2C5H9O3.Cr.Na.O/c2*1-3-5(2,8)4(6)7;;;/h2*3H2,1-2H3,(H,6,7);;;/q2*-1;+4;+1;-1/p-2
• InChI key: NIZKSTMLMALTGU-UHFFFAOYSA-L

Description

Application

Oxidant was reported by the Baran group to promote selective allylic oxidation of a synthetic intermediate derived from (+)-taxadiene en route to the synthesis of (−)-taxyunnanine D.

Two-Phase Synthesis of (−)-Taxuyunnanine D

Safety Information

• Pictograms: GHS03
• Signal Word: Danger
• Hazard Statements: H272
• Precautionary Statements: P220
• Hazard Classifications: Ox. Sol. 2
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable